Thermal expansion and ordering in D2O ice III / IX

DOI

The high-pressure form of solid water, ice III, is the equilibrium phase in contact with liquid water at pressures from about 2.0 - 3.5 kbar. Consequently, its properties are important in calculating the volume changes on freezing of subsurface oceans inside icy planetary bodies and the buoyancy of icy volcanic melts. The incompressibility (bulk modulus) of ice III as found by quantum mechanical simulations is much lower (<60%) than that of the other ice phases at neighbouring pressures and temperatures, but it is not known whether its thermal expansion is similarly "anomalous". We shall use HRPD to investigate metastable ice III (= ice IX, when proton ordered) by high-resolution neutron powder diffraction so as to determine both its thermal expansion and, from accurate structure refinements, the extent of proton ordering in its crystal structure.

Identifier
DOI https://doi.org/10.5286/ISIS.E.84743199
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/84743199
Provenance
Creator Dr Christopher Howard; Professor David Dobson; Dr Dominic Fortes; Professor Ian Wood; Dr Weiwei Wang; Professor Lidunka Vocadlo
Publisher ISIS Neutron and Muon Source
Publication Year 2020
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Photon- and Neutron Geosciences
Temporal Coverage Begin 2017-02-25T08:00:00Z
Temporal Coverage End 2017-02-27T08:00:00Z