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Magnetic and charge ordering, superstructures and diffuse scattering in de-in...
Sodium Cobaltate has a complex phase diagram, exhibiting various phenomena and a kaleidoscope of superlattice diffraction patterns as the concentration of sodium is varied. It... -
Crystal Structure of Green Dioptase
This dataset has no description
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Two-Dimensional Incommensurate Modulation in Melilite
We have prepared large single crystals of the melilite electroltyes Ln1+xCaxGa3O7+d; (Ln = La and Nd; x = 0 and 0.5) using a floating zone mirror furnace. We have characterised... -
Variable Temperature studies of an anomalous proton sponge benzoic acid co-cr...
As part of a long-running programme, we have identified many co-crystallisation systems producing hydrogen-bonded molecular complexes yielding fascinating X-ray diffraction and... -
Reversible B-H Bond Activation at Cationic Rh(III) Centres: Structural Charac...
Catalytic processes leading to the functionalization of organic molecules by boron-containing reagents are highly topical ¿ ranging from transition metal catalysed hydro- and... -
Magnetic order of multiferroic candidate: the frustrated honeycomb antiferrom...
Magnetic materials with strong spin-orbit interactions are drawing strong attention as candidates to show unusual magnetism such as quantum spin liquid stabilised by highly... -
Structural characterization of a fully detuterated manganese Prussian Blue an...
The aim of this proposal is to perform a neutron diffraction determination of the first perdeuterated Mn-Prussian Blue (PB) analogue of composition: Mn(II)3 [Mn(III)(CN)6]2... -
diffuse scattering in PMN-PT crystals
Complex mixed-ion pervoskites, ferroelectric material (1-x)Pb(Mg1/3Nb2/3)O3-xPbTiO3, attract plenty of applications due to high piezoelectric response. The difficulties result... -
The influence of hydrogen bonding on the melting points of sulfonate-based pr...
This dataset has no description
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Detailed characterisation of metastable phase fractions in ZrW2O8
Cubic alpha-ZrW2O8 is the classic example of a material exhibiting the unusual property of negative thermal expansion (NTE). Despite this effect having been discovered 20 years... -
CPRO#1 T=300K wtl=10.0 j:14,14
This dataset has no description
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Structural Studies of PbZr1-xTixO3 Single Crystals: From Local to Macroscopic...
We propose to study comprehensively the structure of single crystal PbZr1-xTixO3 using the high-resolution SXD instrument. A diffuse scattering experiment is also proposed to... -
Exploiting extraordinary flexibility in molecular frameworks: engineering fer...
This experiment is concerned with the response of a high-dielectric constant metal-organic framework (MOF), lead(II) tricyanomethanide, Pb(tcm)2 to applied electric fields.... -
Phonons from diffraction and normal mode analysis in HMT
With the overall aim of extending the information derivable in a neutron single crystal diffraction experiment beyond the static structure, we are proposing to perform a... -
C-H and H-H Binding in Coordinatively Unsaturated Ruthenium Carbene Complexes
Removal of the chloride ligand from the neutral N-heterocyclic carbene complex Ru(IPr)2(CO)HCl (IPr = bis(1,3-(2,6-diisopropylphenyl)imidazol-2-ylidene) by NaBArF4 affords the... -
Long-range cationic ordering in metal-organic perovskite solid solutions
The structure of the metal guanadinium formates is analogous to perovskite; the Cu compound is of particular interest as a potential multiferroic. We have recently demonstrated... -
Charge disproportionation and structural modulation in multiferroic CaMn7O12
Multiferroic materials in which strongly coupled magnetic and ferroelectric order parameters coexist attract considerable interest. Below 90 K, CaMn7O12 possesses the largest... -
Combined neutron and X-ray single-crystal diffraction studies of selected 2-p...
Hydrozones and their metal complexes exhibit subtle redistribution of electron density as a function of substitution, type of the metal center and intermolecular interactions.... -
Diffuse scattering from doped zinc oxide
Zinc oxide is an important wide band gap semiconductor material used in a diverse range of industrial applications, many of which require both n-type and p-type components. It... -
Neutron photocrystallography study of [Ni(dppe)(n1-NO2)Cl]
Photocrystallography is a rapidly developing technique in modern structural chemistry which will result in a paradigm shift in the way that the crystallographic method is...
