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A melanin-inspired pro-oxidant system for dopa(mine) polymerization: implicat...
Melanins are the major determinants of pigmentation of skin, hair and eyes in humans. These pigments originate from the tyrosinase-catalyzed oxidation of tyrosine, leading to... -
Binary colloidal mixtures - SANS contrast variation to study high concentrati...
Mixtures of colloidal particles of essentially two different sizes are commonly used in technological applications such as film formation on surfaces, paper coatings, etc.... -
Understanding Melt Phase Aggregation in Semicrystalline Polymer Blends
We have recently prepared and studied the surface properties of some well-defined multi-end functional polyethylenes. Whilst most of our surface studies indicate that these... -
Metal ion induced condensation of anionic fluorine-based conjugated polyelect...
In the proposed experiments we aim to characterise the structures of aggregate species formed when divalent metal ions, such as calcium(II), interact with the anionic conjugated... -
Close control over microemulsion stability using blended solvents
The aim of this proposal is to investigate a novel approach to phase separation in microemulsions using careful choice of organic solvents, and appropriate mixtures.... -
Tuning micellar interfacial curvature in CO2 by small molecule additives
This proposal aims to explore co-surfactants, as additives with CO2-active surfactants, for elongating reversed micelles in dense CO2 by using high-pressure small-angle neutron... -
Structure in Polymer Conetworks
This proposal is part of a new research programme at Reading which is focused on a new types of macromolecular structures namely conetworks and pseudo-conetworks. These are... -
Novel gels with supercritical carbon dioxide
This proposal is to probe the gel structure with High Pressure SANS (HP-SANS) using an in-line pressure cell. The ability to control the properties of supercritical CO2,... -
Opening up microemulsion phases in CO2
New types of water-in-CO2 microemulsions using mixed surfactant systems will be investigated by high-pressure SANS (HP-SANS). Exciting new results (see report on RB820030) have... -
Telechelic Polymer - Homopolymer Blends
We have recently embarked on a new 1 year project funded by Michelin to explore the self-associatation and mechanical properties of telechelic rubbery materials. Such materials... -
Composite Electrospun Fibres based on Food waste
Thus proposal seeks to explore the nature of electrospun composite fibres where the polymeric material contains a substantial quantity of biopolymer obtained from food waste -... -
Gelation and spin crossover transitions in gels formed from 1d metallo-organi...
This proposal is part of a research programme at Reading which is focused on thermoresponsive supramolecular gels formed from self-assembling metallo organic polymers. These... -
SANS study of engine oil gelation
Metal carbonate particles dispersed in dodecane and stabilised with alkyl salicylate surfactants have been shown to aggregate when trace water is added. We have found that... -
The formation of elongated aggregates in supercritical CO2 through the mixing...
This proposal involves manipulating the curvature of aggregated polar materials in supercritical CO2 (scCO2) by tuning the mixing ratio of fluorocarbon (FC) and hydrocarbon (HC)... -
Small-Angle Neutron Scattering studies of a bacterial colonization factor
We plan to carry out SANS experiments on a bacterial colonization factor to elucidate how it interacts with chitin, which is found on the surface of plankton and crustaceans.... -
New surfactants forming anisotropic micelles and microemulsions in CO2
An analogue of the popular surfactant AOT with isopropyl glycol tails (IG-AOT, Figure.1) has been recently designed as a co-surfactant for water-in-CO2 (w/c) systems: stable... -
Kinetic Study of the Mechanistic Complexation Process Between DNA and Cationi...
We propose to use the new SANS2d to study the dynamic structural evolution in the couse of the formation of DNA-cationic polymer complexes. The dynamic process and the mixing... -
Mixed micelles with green surfactants
This proposal aims to explore aqueous phase structures and compositions of a series of mixed surfactants. Although standard petrochemically-derived surfactant mixtures have been... -
Polystrene chain conformations in good solvents and electrospun fibres
This proposal is centered on the preparation of nanoscale fibres prepared by electrospinning and is the focus of the final year PhD programme of Saeed Mohan. These experiments... -
Characterization of heterogeneous solvent structure in a carbon capture fluid
We propose to use neutron scattering experiments to gain molecular level insight into an intriguing liquid structure observed in a water-free CO2-capture solvent. Switchable...
