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Towards the development of carbonitrides as novel two-stage regenerable reage...
We are examining a number of cobalt-molybdenum carbonitrides as possible catalysts for reactions that produce nitrogen-containing organic molecules. There is good evidence that... -
Commissioning of copper van-can heaters
This dataset has no description
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A High pressure investigation of the Binary carbonyls of group 7 M2(CO)10 M =...
The structures of two binary metal carbonyls containing a metal-metal bond Mn2(CO)10 and Re2(CO)10 will be studied as a function of pressure. Both these molecules undergo a... -
In-situ Formation of Fast Lithium Conducting garnets via low temperature sol-...
Increasing global population, global warming and depletion of fossil fuels have resulted in a growing need for better energy storage. Lithium-ion batteries are promising devices... -
Kinetics of Hydrogen Abstraction by Mu Reactivity with Propane studied by RF ...
Hydrogen abstraction reactions are key steps in free radical mechanisms that dominate the combustion and atmospheric chemistry of the alkane hydrocarbons and, as such, merit... -
Magnetic structure below the metal-insulator transition of Pb2CaOsO6
This proposal is part of a project in which we explore the unusual physics of 5d transition metal oxides. Using a special high pressure technique, we have synthesised first... -
The crystal structure and thermal expansion of orthorhombic NiSi
NiSi is a technologically important material that is also of interest to Earth Scientists because of the possible role of Ni and Si in the Earth¿s core. It crystallises in the... -
A SANS Study on the Influence of Shear on Peptide Fibrillisation
Time-resolved SANS will be performed to investigate the effect of shear on the fibrillisation of insulin following denaturation. The rheological response will be measured... -
Does the viscosity of the sub-phase effect the oxidation kinetics of surface ...
Atmospheric climate change is strongly influenced by clouds and the oxidative processing of pollutants in clouds affects droplet size and reflectivity of the planet. Clouds... -
Crystal structures of methanol mono-ammoniate (CD3OD.ND3) and methanol hemi-a...
Mixtures of methanol with water and ammonia dominate the chemistry of cometary bodies, leftovers of the building blocks of the outer planets. We have previously determined the... -
Vibrational Spectroscopic Analysis of NbOPO4Hx and Ru/NbOPO4Hx catalysts for ...
Lignin valorization is receiving increasing attention. We request 7 days on TOSCA to carry out inelastic neutron scattering (INS) study of two key chemical processes in lignin... -
Materials Testing for gaskets and anvils
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In Situ High Pressure NMR study of the Direct Synthesis of NaAlH4
NaAlH4 has been a model system for metal hydride hydrogen storage materials since the reaction was identified to be reversible. The decomposition pathway has been described by a... -
Pressure-induced proton migration in an energetic co-crystal
The results of these studies will provide valuable information on the effects of extreme conditions on the structures of an energetic salt and co-crystal formed between... -
Programme Access Rosseinsky
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A single-crystal sapphire cell for in situ powder diffraction on a TOF spectr...
Many technologically important processes from ore smelting to hydrogen storage and the synthesis of functional materials rely on solid-gas reactions. Following these reactions... -
Magnetic Transition in Li-MeNH2
Previously we completed an experiment on ARGUS to determine the extent of magnetic transitions in Li(MeNH2)4. This experiment was designed to overcome sample environment... -
Molecular Mechanisms of Enhanced Thermal Conductivity in Copper-based Nanofluids
The combination of the transport properties of liquids with the high thermal conductivity of metals is a promising way of improving heat transfer efficiency and thus reduce... -
Unpicking the signal of partial order from thermal motion in diffuse scatteri...
Orientationally-disordered water molecules in ice adopt a degree of partial order upon cooling, a process that is halted by kinetics at ~100 K in pure ice and ~60 K in KOH-doped... -
In-situ Hydrogenation of Calcium Nitride
Nitrides of alkali and alkaline earth metals are an interesting set of materials specifically for their potential in reversible hydrogen storage. However, many fundamental...
