A single-crystal sapphire cell for in situ powder diffraction on a TOF spectrometer

DOI

Many technologically important processes from ore smelting to hydrogen storage and the synthesis of functional materials rely on solid-gas reactions. Following these reactions in situ (under gas pressure and increased temperature) allows to unravel their basic steps and helps to gain better control over the processes. We have constructed a gas-pressure cell based on a single-crystal sapphire tube as sample holder for in situ studies. The key idea is to completely avoid background contribution of the container (sapphire) in the experiment by proper orientation of the cell. This will eliminate Bragg peaks from the container material and increase data quality considerably. If tested successfully, the single-crystal sapphire cell may be used at ISIS for in situ investigations on a variety of solid-gas reactions.

Identifier
DOI https://doi.org/10.5286/ISIS.E.99687870
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/99687870
Provenance
Creator Professor Paul Henry; Professor Holger Kohlmann; Dr Henry Auer
Publisher ISIS Neutron and Muon Source
Publication Year 2021
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Chemistry; Natural Sciences
Temporal Coverage Begin 2018-11-30T08:00:00Z
Temporal Coverage End 2018-12-14T16:40:12Z