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New CO2-philic surfactants
The proposal aims to explore water-in-CO2 (w/c) microemulsions with new, very promising hydrocarbon surfactants. The compounds are generated using standard chemistry1 but with... -
Rod-like micelles as CO2 fluid thickeners
Using LOQ, we have recently shown that self-assembly of fluoro-sulfocuccinate surfactants is indeed a viable approach to promote viscosity enhancement in liquid CO21 (Rod-like... -
Structural development in Whey protein polymer composite solutions for electr...
This is part of an on-going investigation into nano/micro scale sized polymer fibres at the University of Reading, prepared through the process of electrospinning. Currently we... -
Aggregation in ionic liquids
The aim of this experiment is to investigate surfactant aggregation in ionic liquids and also ionic liquid ¿ oil and ionic liquid ¿ water microemulsions via SANS. Contrast... -
Exploring the exact morphology and self assembly characteristics of novel pol...
We would like to use SANS to explore the mechanism for preparation and properties of cylindrical micelles. We hope to obtain key information relating to the growth mechanism... -
Membrane perturbation and permeabilization by the lysosomotropic detergent MSDH
Lysosomes are subcellular organelles with acidic interiors (pH 3.5-5), containing enzymes that break down macromolecules and intracellular waste. Controlled release of lysosomal... -
Surfactant mixtures including a newly designed N-oxide
The applications of surfactant formulations based on N,N dimethylalkylamine oxides (AO) are dramatically increasing. The most widely used AO is the N,N-dimethyldodecyl-1-amine... -
Photo-reactive surfactants for nanoparticle generation
The aim is to employ contrast variation CV-SANS to investigate structure in novel systems used to generate metal-containing nanoparticles on organic solvents by UV irradiation.... -
Controlled release from lipid-alkylglycoside vesicles, as triggered by amylas...
The consumer demands for functional food have increased the interest for encapsulation of bioactive compounds in the food industry. Encapsulation is crucial, since these... -
Understanding nanoscale inhomogeneities in industrial films
The world wide trade in chemicals is shipped via large tankers. These tankers have their holds coated in epoxy resin based systems. The major issue in their use is the waste and... -
Optimising chemical structure of CO2-philic hybrid surfactants for stabilisin...
The proposal aims to explore water-in-CO2 (w/c) microemulsions with very promising hybridCO2-philic surfactants. The surfactants have been systematically synthesised... -
SANS Studies of Radiation-grafted Anion-exchange Membranes with Different Gra...
We request one days beam time on SANS2D for the study of hydrated, radiation-grafted anion-exchange membranes synthesised with different grafting times. These materials are... -
Structure and formation of L3 phase surfactant templated inorganic oxides
The L3 (sponge) surfactant phase is a promising template for inorganic materials since it is composed of large, uniform water-filled pores separated by a surfactant bilayer. If... -
Inverse Metallosurfactants and Metallomicroemulsions
Incorporation of d- or f-block metals into ligand systems that renders a metal complex surface active or drives its partitioning into surfactant phases enables the localisation... -
Co-existing Hydro/Fluorcarbon Microemulsions for Lanathanide Emission Enhance...
Very recently (April) we undertook a SANS experiment (RB1110147) to probe the partitioning of metal-acac ligand complexes in complex microemulsion media. Our aim was to design a... -
Change in conformation of a chiral poly(2-oxazoline) induced by temperature o...
The aim of this experiment is to investigate the change in conformation of a chiral polymer dissolved in hexafluoroisopropanol as the temperature of the system is varied.... -
Aggregation of Polar Multi-end Functional Polymers
Polar functional groups on polymer chains are of particular interest for applications in adhesion, printing, biocompatibility and mineralisation. We have created a series of... -
Using SANS to understand the structural basis for the rheology of molten choc...
Molten chocolate is a semi-solid suspension of (mostly) sugar, but also cocoa and milk solids in oil. In order to allow the sugar grains to flow past each other, either when the... -
Micellization in glycerol:choline chloride deep eutectic solvent
Deep Eutectic Solvents (DES) are molecular mixtures with melting points below room temperature. DES share many features of ionic liquids (low vapour pressure, adjustable... -
A melanin-inspired pro-oxidant system for dopa(mine) polymerization: implicat...
Melanins are the major determinants of pigmentation of skin, hair and eyes in humans. These pigments originate from the tyrosinase-catalyzed oxidation of tyrosine, leading to...
