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Ferroelectric transitions in potentially multiferroic Mn-formate frameworks
The perovskite-like family of ammonium formate frameworks AB(HCO2)3, where A is a divalent metal ion and B is an (alkyl)ammonium or guanadinium, is of great interest for its... -
The Dynamics of Breathing Metal-Organic Frameworks from Total Scattering
Metal-organic framework materials are a family of nanoporous solids that have potential applications in molecular storage, separation and catalysis. Some of these materials show... -
Structures of New Doped RuO2 Rutiles
We have prepared some new mixed-metal oxides using a chemical synthesis approach that provides access to materials not seen using other techniques. The materials are potentially... -
Structural and Magnetic Characterisation of a Novel Magnetic MOF
Metal organic framework (MOF) materials are porous solids formed from a network of metal centres mainly coordinated to organic linkers. Examples of magnetic MOFs with strong... -
Investigation of the Negative Thermal Expansion in (Sr,Ca)FeO2 with FeO4 squa...
SrFeO2 bears a square planar oxygen coordination around Fe2+. The rarity of this structure led us to study the substitution of strontium by calcium and we obtained the solid... -
Effects of Local Displacements on Phase Transitions in Sr- and Ca-substituted...
Ferroelectric BaTiO3 (BT) constitutes a base system for many practical applications ranging from classical capacitors to tunable dielectrics. A dielectric response in BT is... -
Structural development during crystallisation of synthetic polymers
We wish to exploit the unique capability of Nimrod to move forward the long standing issue of the way in which long chain polymers crystallise. There are two key length scales:... -
Local structure, dynamics and magnetism of the phases of cobalt imidazolate
This proposal concerns the metal-organic framework (MOF), cobalt imidazolate. Imidazole (im) is a small, flat organic molecule that forms slightly bent metal-im-metal linkages,... -
Structural study of oxygen ion conduction in microporous Mayenite
The crystal unit cell of mayenite, 12CaO.7Al2O3, consists of a cubic lattice of [Ca24Al28O64]4+ with the remaining 2*O2- contained in cages, which are linked by channels within... -
Micro-, Meso-, Macro- Structure and Dynamics of Biocompatible Dental Glass Io...
Glass Ionomer Cements (GICs) have found numerous applications as bone fillers, replacements and adhesives, particularly in dentistry due to their tooth like appearance and... -
Composition dependent structure in mixtures of water and hydrogen bonded mono...
This is part of a project concerning the interplay between water and other H-bonded liquids using a range of complementary experimental techniques, e.g. dielectric spectroscopy,...
