Structural and Magnetic Characterisation of a Novel Magnetic MOF

DOI

Metal organic framework (MOF) materials are porous solids formed from a network of metal centres mainly coordinated to organic linkers. Examples of magnetic MOFs with strong magnetic interactions as a result of 3D superexchange are rare. We have prepared a new MOF material Fe2F5(Htaz) that realises a 3D inorganic network containing Fe(II) and Fe(III) cations. Magnetic susceptibility indicate the dominance of strong antiferromagnetic correlations within Fe2F5(Htaz) and the system appears to undergo an ordering transition at ~ 100 K to a ferrimagnetic state. We request one day on GEM to investigate the evolution of spin order in this new magnetic MOF material as a function of temperature.

Identifier
DOI https://doi.org/10.5286/ISIS.E.60997113
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/60997113
Provenance
Creator Professor Jean-Marc Grenèche; Ms Vanessa Pimenta; Dr Jérôme Lhoste; Ms Marjorie Albino; Professor Phil Lightfoot; Dr Marc Leblanc; Dr Lucy Clark; Professor Vincent Vincent Maisonneuve; Dr Annie Hémon-Ribaud
Publisher ISIS Neutron and Muon Source
Publication Year 2018
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Chemistry; Natural Sciences
Temporal Coverage Begin 2015-06-11T07:00:00Z
Temporal Coverage End 2015-06-12T07:00:00Z