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Crystal and Magnetic Structures of Ba2BTeO6 (B=Cu, Ni, Zn)
Ba2CuTeO6 and Ba2NiTeO6 are compounds with structures related to that of the proposed spin liquid Ba3CuSb2O9. The space group and nature of the B-site ordering in Ba3CuSb2O9... -
Understanding negative compressibility in KMn[Ag(CN)2]3
Negative linear compressibility (NLC) is the phenomenon whereby at least one of the linear dimensions of a material actually expand under hydrostatic pressure. It is only... -
Crystal structure of mallardite, manganese sulfate heptahydrate
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Neutron Diffraction Study of a Spin-1/2 Pyrochlore Lu2Mo2O5N2
Ammonolysis of R2Mo2O7 pyrochlores gives R2Mo2O5N2 containing S = ½ Mo5+. They are excellent candidate materials for investigation of quantum spin liquid phenomena and we have... -
Impact of Jahn-Teller Distortions in Sr0.5Pr0.5MnO3
We propose to use the HRPD to establish the sequence of structures, and the nature of the transitions between these, in two complex manganites Sr0.5Pr0.5MnO3 and... -
Programme Access Rosseinsky
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How molecular solids prepare for phase transitions: The phase transition in o...
Oxalyl chloride, which is a liquid at RT, forms a disordered phase (I) on cooling to 260 K. This phase is unstable with respect to an ordered phase (II) below 250 K, but in... -
Uptake of Molecular Hydrogen by High-performance Carbon Nanostructures (IRIS)
High sorption capacities and enhanced interaction strengths are the two most fundamental prerequisites for the deployment of carbon-based materials as hydrogen-storage media. In... -
Magnetic excitations in mesoporous hematite
We have recently prepared mesoporous forms of various metals oxides. In some cases the imposition of a mesostructure changes other properties of the material significantly. One... -
Investigation of antiferromagnetic long-range interactions in Co-based Heusle...
Ni-Mn based Heusler alloys with composition related to the stoichiometry Ni2MnX, with X belonging to the IIIA-VA chemical species, are widely considered as a class of... -
Magneto-elasticity, metamagnetism and the magnetic cooling potential of Fe2P-...
We wish to trace the changes in lattice parameters and atomic coordinates around the first and second order Curie transitions of Fe2P and boron (11B)-doped Fe2P0.95,B0.05... -
Understanding quantum and classical proton transfer mechanisms in protic ioni...
Considerable research efforts have been devoted to polymer electrolyte membranes fuel cells. It has been recently proposed as a promising approach to replace aqueous... -
Exploration of the microscopic origins of thermal anomalies observed in molec...
It is a well established fact that several molecular liquids experiences a series of thermal anomalies as measured by microscopic and macroscopic techniques. A remarkable case... -
Dynamics of Poly Dimethyl Amino Ethyl Methacrylate / water glycerol mixtures
We want to study the microscopic mechanisms of solvent dynamics such as water and glycerol in ahydrophilic polymer. Dielectric measurements suggest that below the glass... -
Structure and magnetism in Sr2IrO4 - benefits of 193Ir use
We plan to investigate the use of the isotope 193Ir for studies of magnetism in iridium containing materials using Sr2IrO4 as a test case. This isotope is important for neutron... -
Strain effect on the magnetic ground state of the ferroelectric Ca3CoMnO6 system
The search for new ferroelectric materials, where the ferroelectricity results from magnetic frustration, has been a topic of great interest to the condensed matter physics... -
Thermal expansion of kyanite, andalusite and sillimanite
Al2SiO5 forms three naturally-occurring polymorphs, kyanite, andalusite and sillimanite. These minerals are produced by varying degrees of metamorphism of sedimentary rocks, the... -
Understanding the formation of diamonds: Calibrating the coesite solid-inclus...
Diamonds provide our only direct samples of the very deep Earth and understanding their origin is consequently of great interest to Earth Scientists. The origin of diamonds can... -
Confined water in a geo-polymer system
The main objective of this proposal is to investigate the dynamics of ultra-confined water in the slits pores of geological cavities (mineral tobermorite). This system provides... -
Structural and magnetic characterisation of polar magnetic perovskite-based m...
A new generation of low-power high-density information storage would be enabled by the development of ?multiferroic? materials which function at or above room temperature. Such...