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Generalising the link between catalytic activity and low-energy normal modes ...
Our recent theoretical and experimental characterisations of novel Pd N-heterocyclic carbene catalysts showed a clear relation between low-energy normal mode energies and... -
Investigation of the ligand interaction in thiol-capped Au and Pd nanoparticl...
Organic stabilisers, such as thiols, thioethers, amines and polymers (i.e. polyvinylalcohol) have been used for the stabilisation of metal nanoparticles. The catalytic... -
The application of INS to examine high specification Fe Fischer-Tropsch catal...
Over the last 4-5 years the research team have been developing INS methodology that can be applied to investigate Fe Fischer-Tropsch (F-T) catalysts. The first stage of that... -
Polymer layer structure in stabilised metal nanoparticles for heterogenous ca...
The controlled synthesis of precious metal nanoparticles of the appriopriate chemical composition, optimised size and morphology for use in catalysis is an ongoing experimental... -
Experimental evidence for quadrupolar order in the heavy fermion compound Ce3...
This proposal aims to probe the quadrupolar order believed to exist in the heavy fermion compound Ce3Pd20Si6 (CPS). Two phase transitions have been uncovered (in zero applied... -
INS study of the effect of particle size on the formation of beta-palladium h...
Finely divided, supported palladium particles are used as catalysts in many technical processes. However, there is still considerable potential to improve catalyst performance... -
Probing of hydride phase formation of Pd nanoclusters embedded in the NH2-UiO...
With this proposal, we would like to investigate a material that could be used as a catalyst for hydrogenation reactions. A catalyst acts to increase the rate of a reaction by... -
Graphene Surface Functionalisation Effect on Hydrogen Spillover
Hydrogen spillover involves dissociation of molecular hydrogen at the surface of metals, particularly transition metals, followed by migration of the hydrogen atoms across the... -
Investigation of the nature of organic surface species formed on Au-based sup...
The objective of this proposal is to spectroscopically identify the nature of surface species formed during the addition of tert butyl hydroperoxide onto the surface of the... -
Understanding the properties of phosphlipid-homopolymer self assembles
We hope to explore the self assembly properties of a novel chain end functionalised homopolymer to better understand its structure and enable tuning of its properties to enable...