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Cationic & Nonionic Micelles in Deep Eutectic Solvents
Deep Eutectic Solvents (DES) are molecular mixtures similar to ionic liquids, having melting points below room temperature. DES share many of the features of ionic liquids (low... -
Micellization in glycerol:choline chloride deep eutectic solvent
Deep Eutectic Solvents (DES) are molecular mixtures with melting points below room temperature. DES share many features of ionic liquids (low vapour pressure, adjustable... -
Polymer-surfactant films containing glucose sensors and structure directing p...
This proposal continues our research on mesostructured surfactant templated polymer films. The films are robust and form spontaneously at the air-water interface. Recent... -
Effects of Chiral Components on the Structure of Deep Eutectic Solvents
Deep eutectic solvents (DES) are novel liquids composed of inexpensive components, and are non-flammable, with a low volatility. One problem with DES is frequently their... -
PAN-pyrene-micelle based sensors for metal ions
We have been studying the solution interactions leading to formation of solid polymer-surfactant films at the air-solution interface. We want to use the mesostructures in the... -
Nanostructures in hydrophobic deep eutectic solvents
Deep eutectic solvents (DES) are mixtures of organic salts and hydrogen bond donors, that form strongly hydrogen-bonded room temperature liquids. DES share many features with... -
Micelle structures in unequal mixtures of amino-acid surfactants
In a previous proposal we started to study the micellar structures formed from biodegradable surfactants synthesised using amino acids as the headgroups. The aim of this work is... -
Rod-to-Sphere Transition in SDS Micelles in Choline Choride:Urea Deep Eutecti...
Our recent work demonstrates that the details of solvent structure around micelles are accessible using Empirical Potential Structure Refinement methods combined with neutron... -
Neutron reflection from nanoparticles interacting with insoluble monolayers
Cell-nanoparticle interactions are complex, involving several specific and non-specific intermolecular forces between a wide range of particulate and molecular species . There... -
Atomic structure of an isooctane/AOT/water reverse micelle
Micelles and reverse micelles have been studied for a long time using small angle scattering techniques. Information extracted from such studies might typically be in the form... -
Mesostructured titania films from ethanolic solutions
In this proposal we wish to continue our current work on mesostructured inorganic films in largely ethanolic solutions, containing limited amounts of water. Transition metal... -
Structure and formation of L3 phase surfactant templated inorganic oxides
The L3 (sponge) surfactant phase is a promising template for inorganic materials since it is composed of large, uniform water-filled pores separated by a surfactant bilayer. If... -
Surfactant induced gelation of TEMPO-oxidized cellulose; Using betaine-based ...
Our group has been working cellulose nanofibrils (OCNF) which form hydrogels in the presence of certain additives. Previously, we have studied the effect of salt, single... -
Water Binding and Solvent Dynamics in Natural Deep Eutectic Solvents
Deep Eutectic Solvents (DES) are molecular mixtures similar to ionic liquids, having melting points below room temperature. However instead of being composed of a salt, the... -
Investigation of zwitterionic surfactant, Ca2+ and bio-polymer interactions
We are currently investigating the formation and structure of surfactant-templated polymer films comprised of cat-anionic surfactant mixtures and a variety of polymers. As we... -
Self-assembly of Polyoxometallate Surfactants in Aqueous Solutions
Polyoxometallates (POM) are well defined transition metal clusters with a range of interesting catalytic, magnetic and optical properties. To make efficient use of these... -
Anion effects on self-assembly in deep eutectic solvents.
Deep Eutectic Solvents (DES) are mixtures of an organic salt with a hydrogen bond donor that form strong interactions which hinder crystallisation. DES share many features with... -
Lipid-polymer nanodiscs stabilized with novel sytrene-maleic anhydride derive...
Polymer stabilized lipid nanodiscs offer enormous potential as tools for enabling membrane protein structural studies & biophysics. Previously we studied nanodisc formation... -
Structural Studies of Mixed Monolayers of Sulfobetaines with Phospholipids
Sulfobetaines are zwitterionic surfactants where the headgroup charges are arranged in the opposite manner to those found in phosphotidylcholine lipid headgroups. Sulfobetaines... -
Ion Binding in Tetradecyltrimethylammonium Surfactant Micelle Solutions
This proposal continues our studies of surfactant micelles using NIMROD, to obtain previously inaccessible details of headgroup-ion interactions. In our previous experiments...