Crystallographic Basis for the High Temperature, 2D Invar Effect in Copper Gillespite-structured Phases

DOI

We wish to study the gillespite-structured phase Ba0.5Sr0.5CuSi4O10 at high temperatures to determine the structural basis of the invar-like (zero thermal expansion) of the a-b plane. Our earlier work has shown that the structural response at low temperature is dominated by low frequency lattice modes with Eg symmetry, and a rigid unit mode model has been developed to characterise gillespite structured phases. One aspect of this model has been the prediction that Ba0.5Sr0.5CuSi4O10 would exhibit invar-like behaviour, possibly extending to high temperature (an observation made on BaFeSi4O10 many years ago, but unexplained at the time). We propose to characterise Ba0.5Sr0.5CuSi4O10 in the temperature range 298 K - 1273 K to study the extent of the invar-like behaviour, to characterise deviations from our rigid-mode model, and to examine any tendency towards our proposed aristotype phase.

Identifier
DOI https://doi.org/10.5286/ISIS.E.47622186
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/47622186
Provenance
Creator Professor Michael Henderson; Dr Kevin Knight
Publisher ISIS Neutron and Muon Source
Publication Year 2017
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Photon- and Neutron Geosciences
Temporal Coverage Begin 2014-03-20T00:00:00Z
Temporal Coverage End 2014-04-01T07:28:06Z