A detailed photometric and spectroscopic analysis of cool (T_eff_<~12000K) white dwarf stars is presented. The sample has been drawn from the Yale Parallax Catalog and from a proper motion survey in the southern hemisphere. Optical BVRI and infrared JHK photometry, as well as spectroscopy at H{alpha}, have been secured for a sample of 152 white dwarfs. The discovery of seven new DA white dwarfs, two new DQ white dwarfs, one new magnetic white dwarf, and three weak magnetic white dwarf candidates, is reported. Our sample also identifies 19 known or suspected double degenerates.