NGC 6231 is a young cluster (age ~2-7 Myr) dominating the Sco OB1 association (distance ~1.59 kpc) with ~100 O and B stars and a large pre-main-sequence stellar population. We combine a reanalysis of archival Chandra X-ray data with multiepoch near-infrared (NIR) photometry from the VISTA Variables in the Via Lactea (VVV) survey and published optical catalogs to obtain a catalog of 2148 probable cluster members. This catalog is 70% larger than previous censuses of probable cluster members in NGC 6231. It includes many low-mass stars detected in the NIR but not in the optical and some B stars without previously noted X-ray counterparts. In addition, we identify 295 NIR variables, about half of which are expected to be pre-main-sequence stars. With the more complete sample, we estimate a total population in the Chandra field of 5700-7500 cluster members down to 0.08 M_{sun} (assuming a universal initial mass function) with a completeness limit at 0.5 M{sun}_. A decrease in stellar X-ray luminosities is noted relative to other younger clusters. However, within the cluster, there is little variation in the distribution of X-ray luminosities for ages less than 5 Myr. The X-ray spectral hardness for B stars may be useful for distinguishing between early-B stars with X-rays generated in stellar winds and B-star systems with X-rays from a pre-main-sequence companion (>35% of B stars). A small fraction of catalog members have unusually high X-ray median energies or reddened NIR colors, which might be explained by absorption from thick or edge-on disks or being background field stars.

Cone search capability for table J/AJ/154/87/table1 (*X-Ray Sources and Properties)

Cone search capability for table J/AJ/154/87/table3 (NGC 6231 CXOVVV Probable Cluster Member Catalog)

Cone search capability for table J/AJ/154/87/table4 (VVV K_s_-band Variables)

Cone search capability for table J/AJ/154/87/table5 (Chandra X-ray properties of OB stars)