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Determination of the location of molecular hydrogen trapped within a metal-or...
An interesting In(III)-framework has been synthesized at the University of Nottingham by the group of research of Martin Schroder. This metal-organic framework is based on... -
Adsorption of tetraalkylammonium (R4N+) counterions into monolayers of surfac...
This proposal is to explore adsorption of tetraalkylammonium (R4N+) counterions into monolayers of surfactant anions (see Figure 1) at the air-water interface, as a function of... -
Adsorption of magnetic surfactants
Surfactants responsive to pH, temperature, CO2, and light are known, however, our recent work has shown, for the first time surfactants that are magneto-responsive, and also... -
Mechanism of charging metal oxide colloids in non-polar solvents
Contrast-variation SANS (CV SANS) will be used to determine how surfactant inverse micelles interact with model metal oxide colloids. By using deuterated surfactant (D-AOT) with... -
Vibrational spectra of acetylene in a novel iron metal-organic framework for ...
The energy costs associated with large-scale industrial separation of light hydrocarbons by cryogenic distillation could potentially be lowered through development of selective... -
Optimizing surfactants for CO2
This experiment addresses an important, and still unresolved, question in the field CO2-philic surfactants: what is the minimum fluorine content necessary to obtain a CO2-philic... -
Effect of electrochemical control function and dopant anion on polyaniline fi...
We propose to determine the structures (polymer and solvent populations and spatial distributions) of polyaniline films deposited by different protocols. These involve different... -
Magnetic self-aggregating ionic liquids (MSAILs)
This proposal is to explore aqueous phase structures with a new class of magnetic self-aggregating ionic liquids (MSAILs) (see Figures 2 and 3 below). The dilute micellar... -
Using SERGIS, SESANS and NR to probe nanoscale cavities created within templa...
Nanoporous membranes fabricated by polymerization around soluble templates have found many applications in (bio)sensors, charge storage devices, filtration and catalysis.... -
Vibrational Densities of States from Amorphous Nanocomposites for Novel Drug ...
In the current proposal, we require TOSCA to investigate by vibrational spectroscopy the apparent amorphous nature of the prototype drug molecule ibuprofen confined by... -
Microemulsions stabilized by magnetic surfactants
Surfactant systems responsive to pH, temperature, CO2, and light are known. Our new work has shown for the first time, magneto-responsive surfactants (also being ionic liquids... -
Do hydrotropes stabilize, or destabilize, micelles?
The aim is to investigate and understand interactions of hydrotropes (primitive amphiphiles) with a new range of industrially important non-ionic surfactants, alkyl-capped... -
Crystal structure and Li/O ordering of Li18Fe7La36O73.5
This dataset has no description
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Photo-reactive surfactants for nanoparticle generation
The aim is to employ contrast variation CV-SANS to investigate structure in novel systems used to generate metal-containing nanoparticles on organic solvents by UV irradiation.... -
Metallomicroemulsions - a new class of supramolecularly organised metal ions
Incorporation of d- or f-block metals into ligand systems that renders a metal complex surface active or drives its partitioning into surfactant phases enables the localisation... -
Vibrational shifts of CO2 captured in metal-organic frameworks
High surface area, functionalized metal-organic frameworks (MOF) have been shown to not only capture CO2, but to selectively do so over other gases like nitrogen. There are both... -
Co-micellization of hydrotropes and surfactants
This proposal builds on recent work with hydrotropes alone (Langmuir, 2011, 27, 12346-12353); now co-micellisation of hydrotropes with surfactants will be investigated. The aim... -
Gels in CO2
The proposal aims to explore different self-assembly structures in CO2 with the focus of developing viscosity modifiers for supercritical CO2 (sc-CO2). This is part of a... -
Polymer-induced critical pase separation
This proposal concerns a novel approach to phase separation in self-assembling colloidal systems. Microemulsions can be readily formulated to display critical-type phase... -
Developing a generic gravimetric method to determine the composition of films...
We propose to develop a new and generic, multi-probe technique to characterize the mass, and changes in mass, of material probed in a NR experiment. This methodology will be...
