Evolution of magnetic ordering in three oxide arsenides containing CrO2 layers: Ba2Cr2MnAs2O2, Sr2CrMn2As2O2 and Sr2Cr2MnAs2O2

DOI

This experiment will probe the evolution of magnetic ordering in compounds with square planar Cr2+ ions in CrO2 oxide layers, and the interaction of these moments with Mn2+ and Cr2+ moments in the intervening (Cr0.5Mn0.5)As or MnAs arsenide layers. The compounds will be compared with the isostructural Ba2Cr3As2O2 and Sr2Cr3As2O2 which have spin reorientation transitions at ~ 300 K due to interplay of the two Cr2+ sublattices. Preliminary single-temperature measurements have been used to examine the obvious question of Cr/Mn order vs disorder showing that Cr2+ is the sole occupant of the oxide layer in all three cases. These measurements furthermore show that all three compounds show magnetic long range order, and the ordered models are different. Thus a full variable temperature probing of magnetic long range order is required.

Identifier
DOI https://doi.org/10.5286/ISIS.E.87813417
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/87813417
Provenance
Creator Dr Fabio Orlandi; Mr Xiaoyu Xu; Dr Simon Cassidy; Dr Simon Clarke; Ms Cristina Castro Vargas; Dr Danny Woodruff; Mr Jack Blandy
Publisher ISIS Neutron and Muon Source
Publication Year 2021
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Chemistry; Natural Sciences; Physics
Temporal Coverage Begin 2018-02-16T08:00:00Z
Temporal Coverage End 2018-02-18T11:09:53Z