Bulk organic carbon and n-alkane composition data for river sediment depth profile samples from the Rio Bermejo (Argentina) collected in March 2017

DOI

We extracted and analyzed n-alkane compounds from river suspended sediment collected from the Rio Bermejo in Argentina. We collected 24 river depth profile samples collected during March 2017. We collected suspended particulate matter from water depth profiles at four locations along the mainstem Rio Bermejo (river km 135, 420, 865, 1220), one location on the Rio San Francisco (RSF) (river km -15), and one location on the Rio Bermejo upstream from the RSF confluence (river km -10) (Fig. 1a). We homogenized and disaggregated the dry sediment using a mortar and pestle, and removed coarse plant material >1 mm. For each sample, we weighed an aliquot of sediment and loaded the material into aluminum cells for lipid extraction. Total lipid extracts (TLE) were recovered using an accelerated solvent extraction system (Dionex ASE) with 9:1 v/v dichloromethane: methanol. We added exactly 10 µg of internal standard (5-a-Androstane) to the TLE for unknown compound quantification. We then separated the TLE into three fractions using silica gel column chromatography with hexane (alkanes), 1:1 v/v hexane: dichloromethane (ketones), and 1:1 v/v dichloromethane: methanol (alcohols + acids) (Rach et al., 2020; doi:10.1016/j.orggeochem.2020.103995). Unsaturated compounds were removed from the alkane fraction using AgNO3-silica gel column chromatography with n-hexane (saturated n-alkanes) and DCM (unsaturated n-alkanes).n-alkanes were identified and quantified using an Agilent gas chromatograph (GC 7890-A) with flame ionization detection (FID) coupled to a single quadrupole mass spectrometer (MS 5975-C). We quantified n-alkane concentrations relative to the peak response of the internal standard, and then normalized the abundance to the sediment mass. We measured n-alkane d13C via GC-C-IRMS (gas chromatography/combustion/isotope-ratio mass spectrometry) with helium as a carrier gas (Agilent 7890N, ThermoFisher Delta V Plus). All compounds were measured in triplicate with a standard deviation of =0.5‰. Measurement quality was checked regularly by measuring n-alkane standards (nC15, nC20, nC25) with known isotopic composition (provided by Campro Scientific, Germany). d13C values were normalized to the Vienna Pee Dee Belemnite (VPDB) standard. We measured n-alkane d2H via GC-IRMS using a ThermoFisher Scientific Trace GC 1310 coupled to a Delta-V isotope ratio mass spectrometer. All d2H measurements were made in duplicate, and measurement quality was checked with d2H values were normalized to the Vienna Standard Mean Ocean Water (VSMOW) standard using an n-alkane standard mix with known d2H values (nC16 - nC30, from A. Schimmelman/Indiana University).

Identifier
DOI https://doi.org/10.1594/PANGAEA.925626
Related Identifier https://doi.org/10.1038/s41561-021-00845-7
Metadata Access https://ws.pangaea.de/oai/provider?verb=GetRecord&metadataPrefix=datacite4&identifier=oai:pangaea.de:doi:10.1594/PANGAEA.925626
Provenance
Creator Repasch, Marisa N ORCID logo; Vieth-Hillebrand, Andrea (ORCID: 0000-0002-3688-662X); Sachse, Dirk ORCID logo; Scheingross, Joel S ORCID logo; Hovius, Niels ORCID logo
Publisher PANGAEA
Publication Year 2020
Rights Creative Commons Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Representation
Language English
Resource Type Dataset
Format text/tab-separated-values
Size 1070 data points
Discipline Earth System Research
Spatial Coverage (-64.184W, -26.661S, -58.635E, -23.251N); General Mansilla; Reserva Natural Formosa; Embarcacion; Rio San Francisco; El Colgado; Puerto lavalle; El Colorado
Temporal Coverage Begin 2017-03-12T00:00:00Z
Temporal Coverage End 2017-03-25T00:00:00Z