A^3^{Pi}-X^3^{Sigma}^-^ transitions of OH+

DOI

The OH^+^ ion is of critical importance to the chemistry in the interstellar medium and is a prerequisite for the generation of more complex chemical species. Submillimeter and ultraviolet observations rely on high quality laboratory spectra. Recent measurements of the fundamental vibrational band and previously unanalyzed Fourier transform spectra of the near-ultraviolet A^3^{Pi}-X^3^{Sigma}^-^ electronic spectrum, acquired at the National Solar Observatory (NSO) at Kitt Peak in 1989, provide an excellent opportunity to perform a global fit of the available data. These new optical data are approximately four times more precise as compared to the previous values. The fit to the new data provides updated molecular constants, which are necessary to predict the OH^+^ transition frequencies accurately to support future observations. These new constants are the first published using the modern effective Hamiltonian for a linear molecule. These new molecular constants allow for easy simulation of transition frequencies and spectra using the PGOPHER program. The new constants improve simulations of higher J-value infrared transitions, and represent an improvement of an order of magnitude for some constants pertaining to the optical transitions.

Identifier
DOI http://doi.org/10.26093/cds/vizier.18400081
Source https://dc.g-vo.org/rr/q/lp/custom/CDS.VizieR/J/ApJ/840/81
Related Identifier https://cdsarc.cds.unistra.fr/viz-bin/cat/J/ApJ/840/81
Related Identifier https://vizier.cds.unistra.fr/viz-bin/VizieR-2?-source=J/ApJ/840/81
Metadata Access http://dc.g-vo.org/rr/q/pmh/pubreg.xml?verb=GetRecord&metadataPrefix=oai_b2find&identifier=ivo://CDS.VizieR/J/ApJ/840/81
Provenance
Creator Hodges J.N.; Bernath P.F.
Publisher CDS
Publication Year 2018
Rights https://cds.unistra.fr/vizier-org/licences_vizier.html
OpenAccess true
Contact CDS support team <cds-question(at)unistra.fr>
Representation
Resource Type Dataset; AstroObjects
Discipline Astrophysics and Astronomy; Interdisciplinary Astronomy; Natural Sciences; Observational Astronomy; Physics