Radiocarbon and thermogravimetric analysis (TGA) results of permafrost leachate from the Lena Delta, Arctic

DOI

This datasheet includes radiocarbon and thermogravimetric analysis (TGA) results of permafrost leachate from samples collected in the Lena Delta. The leaching protocol followed Ksionzek et al. (2018). Around 200 mg of dried sediment was leached in 20 mL deionized water for 24 hours at 4 °C, with intermittent shaking every 6−8 hours. The leachates were filtered through 0.7 μm GF/F filters, acidified to pH 2 using 37% HCl, and analyzed by high-temperature catalytic combustion (Shimadzu, TOC-VCPN). Pretreatment and measurement of radiocarbon analysis followed protocols in Mollenhauer et al. (2021). Freeze-dried leachates were wrapped into silver boats and converted into graphite targets using Elementar vario Isotope coupled to Ionplus AG, AGE-3. Radiocarbon isotopic ratios were measured using MICADAS at AWI, Bremerhaven. For TGA analysis, leachate samples of ~10 mg were analyzed in 70 μL aluminum oxide crucibles using a Mettler Toledo TGA/DSC 1. The samples were heated from 25 to 1000 °C at a rate of 10 °C min-1 under a constant argon flow of 20 mL min-1, following similar settings from Smeaton & Austin (2022). Following Lopez-Capel et al. (2006), weight loss between 200–400 °C is attributed to the decomposition of labile organic matter (OML), while weight loss between 400–650°C corresponds to the decomposition of recalcitrant and refractory organic matter (OMR). The percentage of labile organic matter (OML/OM) is calculated as [OML/(OML+OMR)]*100%

Identifier
DOI https://doi.pangaea.de/10.1594/PANGAEA.984752
Related Identifier IsPartOf https://doi.org/10.1594/PANGAEA.984732
Related Identifier References https://doi.org/10.1016/j.orggeochem.2006.07.025
Related Identifier References https://doi.org/10.1371/journal.pone.0203260
Related Identifier References https://doi.org/10.1016/j.nimb.2021.03.016
Related Identifier References https://doi.org/10.1029/2021GL097481
Metadata Access https://ws.pangaea.de/oai/provider?verb=GetRecord&metadataPrefix=datacite4&identifier=oai:pangaea.de:doi:10.1594/PANGAEA.984752
Provenance
Creator Lin, Tsai-Wen ORCID logo; Nehrke, Gernot ORCID logo; Grotheer, Hendrik ORCID logo; Koch, Boris P (ORCID: 0000-0002-8453-731X); Mollenhauer, Gesine (ORCID: 0000-0001-5138-564X)
Publisher PANGAEA
Publication Year 2025
Funding Reference Helmholtz Association of German Research Centres https://doi.org/10.13039/501100001656 Crossref Funder ID PIE-0018 German-Italian partnership project between AWI and CNR-ISP on Chronologies for Polar Paleoclimate Archives (PAIGE)
Rights Creative Commons Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Representation
Resource Type Dataset
Format text/tab-separated-values
Size 29 data points
Discipline Earth System Research
Spatial Coverage (126.481W, 72.377S, 128.286E, 72.537N); Lena Delta, Siberia
Temporal Coverage Begin 2018-04-13T00:00:00Z
Temporal Coverage End 2019-04-05T00:00:00Z