Local structure of candidate hybrid improper ferroelectrics

DOI

Ferroelectrics are materials that exhibit a switcheable polarisation, i.e. a net displacement of positively charged cations relative to anions that is reversible. In traditional "proper" ferroelectrics, this property is usually associated with the electronic structure of particular cations, but the field has been shaken recently by the discover of the "hybrid-improper" mechanism for ferroelectricity, in which different types of structural changes can be coupled to give rise to this property. We've been working on some materials with the potential to show ferroelectricity by this new mechanism, but our experiments have revealed some disorder in their crystal structures. We believe that this disorder is related to the very same structural changes associated with the mechanism, and neutron scattering experiments to study this are needed to fully understand this behaviour.

Identifier
DOI https://doi.org/10.5286/ISIS.E.89711461
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/89711461
Provenance
Creator Dr Emma McCabe; Professor Martin Dove; Dr Neil Hyatt; Dr Anthony Phillips; Dr Helen Playford; Dr Eric Bousquet; Dr Igor Levin
Publisher ISIS Neutron and Muon Source
Publication Year 2020
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Chemistry; Natural Sciences; Physics
Temporal Coverage Begin 2017-12-09T08:00:00Z
Temporal Coverage End 2017-12-11T09:37:38Z