A QENS Study of Benzyl Phenyl Ether, a Lignin Model Compound, on a Hydrodeoxygenation Catalyst

DOI

Bio-oil is an alternative and renewable energy from biomass, however, its high content of oxygenates result in low heating values and chemical/thermal instability. One effective upgrading process is hydrotreatment using hydrodeoxygenation catalysts. We have synthesised a novel pillared clay catalyst, i.e.NiMoS/PILC and results showed that our catalysts were superior to commercial NiMoS/Al2O3. A crucial step in the reaction sequence is migration of adsorbed species to the active site. QENS is a well-established technique for measuring diffusion of adsorbates in microporous systems. However, it has been much less used for adsorbed species on supported catalysts. In our previous exploratory measurement, we demonstrated the measurement of guaiacol adsorbed on our catalysts. In this continuation we wish to compare the behaviour of benzyl phenyl ether adsorbed on a PILC and and a NiMoS/PILC.

Identifier
DOI https://doi.org/10.5286/ISIS.E.98020310
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/98020310
Provenance
Creator Dr Indri Badria Adilina; Dr Ian Silverwood; Mr Fauzan Aulia; Dr Ferensa Oemry; Dr Nino Rinaldi; Professor Stewart Parker
Publisher ISIS Neutron and Muon Source
Publication Year 2021
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Chemistry; Natural Sciences
Temporal Coverage Begin 2018-10-03T08:30:00Z
Temporal Coverage End 2018-10-10T08:24:40Z