Local atomic and magnetic structure of multiwall carbon nanotubes continuously filled with cementite

DOI

We propose to study a novel nanostructure consisting of multi-walled carbon nanotubes continuously filled with a single crystal of Fe3C using total neutron scattering on NIMROD. The high-purity magnetic core, protected from degradation by the carbon layer, displays anomalous magnetic properties including marked steps in the hysteresis curve and reduced coercivity at low temperatures. These are potentially relevant to technological applications including magnetic data storage and hyperthermia cancer therapy; yet their structural causes are unknown. Our data, modelled using PDFgui and RMCprofile refinement, will provide crucial information for understanding the local magnetic and atomic structure that determines this peculiar behaviour. They will also form part of a broader project aimed at developing methods to accurately model total scattering from nanomaterials.

Identifier
DOI https://doi.org/10.5286/ISIS.E.63529440
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/63529440
Provenance
Creator Dr Maureen Willis; Professor David Keen; Dr Tristan Youngs; Dr Anthony Phillips; Professor Martin Dove; Dr Filippo Boi; Miss Serena A. Maugeri; Dr Daniel Bowron
Publisher ISIS Neutron and Muon Source
Publication Year 2018
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Natural Sciences; Physics
Temporal Coverage Begin 2015-10-08T08:00:00Z
Temporal Coverage End 2015-10-10T08:00:00Z