Evolution of Ni and Co during the direct regeneration of spent ternary cathodes

DOI

In light of environmental protection and resource reutilization, efficiently recycling lithium-ion batteries has become a key issue. In the spent ternary cathode (SNCM523), the oxidation states, symmetry, spin states, and coordination structures of Ni and Co elements undergo significant changes. Specifically, the reduction of Ni³⁺ (d7) and Co³⁺ (d6) oxidation states lead to an increase in unpaired electrons in the eg orbitals, which enhances the super-exchange interaction between Ni²⁺-O-Ni³⁺ and Ni²⁺-O-Co²⁺, thereby exacerbating the Li⁺/Ni²⁺ cation mixing. Traditional XAS provides limited information on transition metal compounds' symmetry, spin, and covalency. In this study, we employ L3-edge RIXS to investigate the evolution of Ni and Co elements during the regeneration of SNCM523, thereby contributing to the rational design of more efficient recycling strategies for SNCM523.

Identifier
DOI https://doi.org/10.15151/ESRF-ES-2064091584
Metadata Access https://icatplus.esrf.fr/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatplus.esrf.fr:inv/2064091584
Provenance
Creator Guanghan ZHU; Zhi CHENG; Xin DENG; Feng Ryan WANG (ORCID: 0000-0002-2475-606X); RACHEL NICKEL ORCID logo; Tongjiang LI
Publisher ESRF (European Synchrotron Radiation Facility)
Publication Year 2028
Rights CC-BY-4.0; https://creativecommons.org/licenses/by/4.0
OpenAccess true
Representation
Resource Type Data from large facility measurement; Collection
Discipline Particles, Nuclei and Fields