With the introduction of mobile mapping technologies, geomonitoring has become increasingly efficient and automated. The integration of Simultaneous Localization and Mapping (SLAM) and robotics has effectively addressed the challenges posed by many mapping or monitoring technologies, such as GNSS and unmanned aerial vehicles, which fail to work in underground environments. However, the complexity of underground environments, the high cost of research in this area, and the limited availability of experimental sites have hindered the progress of relevant research in the field of SLAM-based underground geomonitoring. In response, we present SubSurfaceGeoRobo, a dataset specifically focused on underground environments with unique characteristics of subsurface settings, such as extremely narrow passages, high humidity, standing water, reflective surfaces, uneven illumination, dusty conditions, complex geometry, and texture less areas. This aims to provide researchers with a free platform to develop, test, and train their methods, ultimately promoting the advancement of SLAM, navigation, and SLAM-based geomonitoring in underground environments. SubSurfaceGeoRobo was collected in September 2024 in the Freiberg silver mine in Germany using an unmanned ground vehicle equipped with a multi-sensor system, including radars, 3D LiDAR, depth and RGB cameras, IMU, and 2D laser scanners. Data from all sensors are stored as bag files, allowing researchers to replay the collected data and export it into the desired format according to their needs. To ensure the accuracy and usability of the dataset, as well as the effective fusion of sensors, all sensors have been jointly calibrated. The calibration methods and results are included as part of this dataset. Finally, a 3D point cloud ground truth with an accuracy of less than 2 mm, captured using a RIEGL scanner, is provided as a reference standard.