Determination of the crystal electric field scheme in geometrically frustrated lanthanide garnets

DOI

The magnetic ground state in geometrically frustrated lanthanide oxides is determined by the interplay between different magnetic interactions and crystal electric field (CEF) effects. We have recently the effect of chemical pressure on the magnetic properties of the frustrated lanthanide garnets, Ln3A2X3O12, by varying the non-magnetic cations A and X. Magnetic ordering features are observed for all garnets with Ln = Tb, Dy, Ho; however the nature of ordering varies for different Ln as well as for different combinations of A and X. The magnitude of exchange and dipolar interactions are found to be similar for all the garnets. Therefore it is postulated that the variations in magnetic ordering are caused by subtle differences in the CEF. We propose inelastic neutron scattering experiments on MERLIN to precisely determine the CEF levels for garnets with Ln = Tb, Dy, Ho.

Identifier
DOI https://doi.org/10.5286/ISIS.E.90593274
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/90593274
Provenance
Creator Dr Sian Dutton; Miss Paromita Mukherjee; Dr Helen Walker
Publisher ISIS Neutron and Muon Source
Publication Year 2021
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Natural Sciences; Physics
Temporal Coverage Begin 2018-03-14T09:00:00Z
Temporal Coverage End 2018-03-19T09:28:24Z