A Hexagonal Shape-Persistent Nanobelt of Elongated Rhombic Symmetry with Orthogonal π-Planes by a One-Pot Reaction [Data]

DOI

Triptycenes with their predefined D3h-symmetry are excellent molecular building blocks to construct shape-persistent nanobelts having π-orbitals orthogonal to the ring plane. However, up to now, there are only a very few examples of fused and rigid iptycene nanobelts synthesized in several consecutive steps in overall yields below 1%. Here we present the simple one-step one-potapproach to an iptycene nanobelt, which forms in >2% and can readily isolated from the polymeric by-product by gel-permeation chromatography.

Identifier
DOI https://doi.org/10.11588/data/EBY4AN
Related Identifier https://doi.org/10.1002/ejoc.202101317
Metadata Access https://heidata.uni-heidelberg.de/oai?verb=GetRecord&metadataPrefix=oai_datacite&identifier=doi:10.11588/data/EBY4AN
Provenance
Creator Lauer, Jochen C.; Kohl, Bernd; Rominger, Frank; Mastalerz, Michael
Publisher heiDATA
Contributor Mastalerz, Michael
Publication Year 2022
Funding Reference Deutsche Forschungsgemeinschaft SFB 1249 (TP-A04)
Rights info:eu-repo/semantics/openAccess
OpenAccess true
Contact Mastalerz, Michael (Institute of Organic Chemistry, Heidelberg University)
Representation
Resource Type Dataset
Format application/zip
Size 289815161; 16473105; 16683665; 16334505; 16431729; 16384162; 80159752; 72870251
Version 1.1
Discipline Chemistry; Natural Sciences