Hyper-auxeticity and the volume phase transition of polymer gels

DOI

<p><span>Thermoresponsive hydrogels exhibit reversible deswelling at the volume phase transition (VPT), associated to a minimum of the Poisson's ratio <span>ν</span>. Recent numerical investigations uncovered the occurrence of a hyper-auxetic transition (HAT) (<span>ν</span> = −1) for low-crosslinked hydrogels at low temperature, accompanied by a critical-like behavior. Here, we perform extensive numerical simulations to unveil the relation between these two transitions. We find that the HAT occurs at different temperatures <span>T</span> up to a maximum value of the crosslinker concentration <span>c</span>, thus being clearly distinct from the VPT, taking place at fixed <span>T</span> for all values of <span>c</span>. Our results provide novel fundamental insights on the interplay between network collapse and mechanical properties of these fascinating materials.</span></p>

Identifier
DOI https://doi.org/10.24435/materialscloud:vy-c1
Related Identifier https://doi.org/10.1039/D5SM00251F
Related Identifier https://archive.materialscloud.org/communities/mcarchive
Related Identifier https://doi.org/10.24435/materialscloud:wa-k0
Metadata Access https://archive.materialscloud.org/oai2d?verb=GetRecord&metadataPrefix=oai_dc&identifier=oai:materialscloud.org:9ws0f-1gj32
Provenance
Creator Ninarello, Andrea; Zaccarelli, Emanuela
Publisher Materials Cloud
Contributor Zaccarelli, Emanuela
Publication Year 2025
Rights info:eu-repo/semantics/openAccess; Creative Commons Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/legalcode
OpenAccess true
Contact archive(at)materialscloud.org
Representation
Language English
Resource Type info:eu-repo/semantics/other
Format application/zip
Discipline Materials Science and Engineering