This dataset contain all raw datas linked to analysis of synthesized molecules reported in the paper: "Diverse Approaches for the Difunctionalization of PPH Den-drimers. Precise Versus Stochastic: How Does this Influence Catalytic Performance?", published on the journal ACS Macro Letters.

Bruker Topspin, 4.1.1 or higher

MestReNova, 12.0.0 or higher

OriginPro, 8.1 or higher

METHODOLOGICAL INFORMATION: Description of methods used for collection-generation of data: 1H NMR spectra were recorded on Agilent Mercury spectrometers (300 MHz, 400 MHz). Chemical shifts (δ) are reported in parts per million (ppm) downfield from trimethylsilane (TMS) and referred to residual solvent peak: CDCl3 (δH = 7.26 ppm) or DCM-d2 (δH = 5.32 ppm). The spectra were processed using MestReNova software. 13C NMR spectra were recorded at room temperature. Chemical shifts are reported in parts per million downfield from TMS signal and referred to residual peak solvent: CDCl3 (δC = 77.2 ppm) or DCM-d2 (δC = 54.0 ppm). Otherwise stated, the multiplicity refers to 1H decoupled spectra. The spectra were processed using MestReNova software. 19F NMR spectra were recorded at room temperature. Chemical shifts are reported in parts per million. Otherwise stated, the multiplicity refers to 1H decoupled spectra. The spectra were processed using MestReNova software. 31P NMR spectra were recorded at room temperature in CDCl3 or DCM-d2. Chemical shifts are reported in parts per million relative to H3PO4 85% aqueous solution (δP = 0.00 ppm) as an external standard. The spectra were processed using MestReNova software. IR spectra were recorded with on a Bruker Tensor 27 spectrometer fitted with a universal Attenuated Total High-resolution mass spectra (HR-MS) were measured at the Servicio de Espectrometría de Masas at the Universidad de Zaragoza. Elemental Analyses and Inductively coupled plasma (ICP-OES) were measured at the Servei d’Anàlisi Química de l’Universitat Autònoma de Barcelona. Methods for processing the data: NMR and IR are presented Raw. Mass Spectra are presented as a report from Servicio de Espectrometría de Masas at the Universidad de Zaragoza. ICP analyses are presented as a report from the Servei d'Anàlisi Química de la UAB