Substituted Cyclopentannulated Tetraazapentacenes [data]

DOI

Brominated pentannulated dihydrotetraazapentacenes were prepared by gold- or palladium-catalyzed 5-endo-dig cyclization of TIPS-ethynylated dihydrotetraazaacenes (TIPS = triisopropylsilyl). Post-functionalization was demonstrated by Sonogashira alkynylation and Rosenmund-von Braun cyanation. Calculations predict these species to act as n-type semiconductors, which was verified for two derivates through characterization in organic field-effect transistors.

Identifier
DOI https://doi.org/10.11588/DATA/AUTKBW
Related Identifier IsCitedBy https://doi.org/10.1002/chem.202201842
Metadata Access https://heidata.uni-heidelberg.de/oai?verb=GetRecord&metadataPrefix=oai_datacite&identifier=doi:10.11588/DATA/AUTKBW
Provenance
Creator Maier, Steffen
Publisher heiDATA
Contributor Maier, Steffen
Publication Year 2023
Funding Reference Deutsche Forschungsgemeinschaft SFB 1249
Rights CC BY 4.0; info:eu-repo/semantics/openAccess; http://creativecommons.org/licenses/by/4.0
OpenAccess true
Contact Maier, Steffen (Institute of Organic Chemistry, Heidelberg University)
Representation
Resource Type Dataset
Format application/zip
Size 514198292
Version 1.0
Discipline Chemistry; Natural Sciences