Jump diffusion of small molecules in polymers – influence of grafting on the mechanism of diffusion.

DOI

The concept of diffusion of light gases through polymers is a widely used in a variety of commercially available materials - food packaging materials, solar cell encapsulants, industrial separation membranes - with the entire field relying on the assumption that different polymers transport gases at different rates through them. The entire field rests upon the idea that diffusion of gases through polymers operate through a jump diffusion mechanism and by tuning the chemistry of the system, you can alter this and therefore alter the macroscopic diffusion coefficient. Our work aims to show that nanocomposites can solve problems faced by more traditional membranes (loss of function with time, brittleness .etc.) while simultaneously providing an experimental technique to probe the mechanism and measure microscopic diffusion parameters, thus providing a new framework for separation membranes.

Identifier
DOI https://doi.org/10.5286/ISIS.E.RB1910201-1
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/103219250
Provenance
Creator Mr Mayank Jhalaria; Dr Victoria Garcia Sakai; Dr Sanat Kumar
Publisher ISIS Neutron and Muon Source
Publication Year 2022
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Photon- and Neutron Geosciences
Temporal Coverage Begin 2019-06-10T08:30:00Z
Temporal Coverage End 2019-06-17T07:08:31Z