Impact of Diagenesis on the isotope signature of Cretaceous Sponge Spicules from the DSDP Leg 79 Site 545

DOI

Cretaceous siliceous sponge spicules spanning from late Aptian (~ 116-113 Ma) to middle Albian (~109-105 Ma) collected from DSDP Leg 79 Site 545 exhibited two preservation states: visually similar to modern (category 1), or clearly altered towards a milky, translucent composition (category 2). A suite of geochemical and structural analyses (XRD, Raman spectroscopy and FT-IR spectroscopy) was applied to investigate and compare strucutral and chemical changes. The effect of (early) diagenesis on isotope signatures was studied by comparing MC-ICP-MS and SIMS δ30Si and δ18O values of spicules from both categories within single samples.

Identifier
DOI https://doi.org/10.1594/PANGAEA.974250
Metadata Access https://ws.pangaea.de/oai/provider?verb=GetRecord&metadataPrefix=datacite4&identifier=oai:pangaea.de:doi:10.1594/PANGAEA.974250
Provenance
Creator Stamm, Franziska Maria; Pickering, Rebecca A ORCID logo; Frings, Patrick J ORCID logo; Frick, Daniel A ORCID logo; Richoz, Sylvain; Conley, Daniel J ORCID logo
Publisher PANGAEA
Publication Year 2024
Funding Reference European Research Council https://doi.org/10.13039/501100000781 Crossref Funder ID 833454 https://doi.org/10.3030/833454 Impact of diatom evolution on the oceans (DEVOCEAN)
Rights Creative Commons Attribution 4.0 International; Data access is restricted (moratorium, sensitive data, license constraints); https://creativecommons.org/licenses/by/4.0/
OpenAccess false
Representation
Resource Type Dataset
Format text/tab-separated-values
Size 566 data points
Discipline Earth System Research
Spatial Coverage (-9.365 LON, 33.664 LAT); North Atlantic/PLATEAU