Lattice dynamics in the giant barocaloric Ammonium Sulfate

DOI

Given the challenges in providing efficient and non-harmful refrigeration, it is timely to study barocaloric systems, which offer cooling power via the application of pressure, something which is far more trivial to do than applying a magnetic field as required for magnetocalorics. The majority of caloric materials investigated so far have been based on expensive and relatively scarce rare-earths metals. Ammonium sulfate, by contrast, is widely and cheaply commercially available. It has been demonstrated that small changes in hydrostatic pressure drive giant inverse barocaloric effects near the ferroelectric phase transition. It is therefore our aim to investigate the phonon dispersion in this material near the transition to gain insight into the origin of the barocaloric effect. Successful measurements would be extended to applying hydrostatic pressure in the future.

Identifier
DOI https://doi.org/10.5286/ISIS.E.99687416
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/99687416
Provenance
Creator Mr Guanqun Cai; Mr Shurong Yuan; Dr David Voneshen; Dr Helen Walker; Dr Anthony Phillips; Dr Richard Dixey; Miss Bernet Meijer
Publisher ISIS Neutron and Muon Source
Publication Year 2021
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Natural Sciences; Physics
Temporal Coverage Begin 2018-11-29T09:00:00Z
Temporal Coverage End 2018-12-04T09:00:00Z