Unravelling the origin of high-temperature magnetic bistability in dysprosocenium

DOI

In the last 25 years the highest blocking temperature TB achieved for the best performing molecular nanomagnets has only reached few K. The situation has recently changed abruptly, with observation of magnetic hysteresis at 60 K in the dysprosocenium nanomagnet. Magnetic measurements and ab initio calculations suggest that the origin of this astonishing increase in TB is related to the coupling of the molecular spin with the constrained metal-ligand vibrational modes. We propose to use MERLIN to measure the phonon density of states and CF excitations to understand the origin of the high-temperature magnetic bistability of dysprosocenium and model its relaxation dynamics.

Identifier
DOI https://doi.org/10.5286/ISIS.E.92923034
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/92923034
Provenance
Creator Dr Nicholas Chilton; Dr Emilio Macaluso; Professor Stefano Carretta; Professor Paolo Santini; Dr Elena Garlatti; Dr David Mills; Dr Tatiana Guidi
Publisher ISIS Neutron and Muon Source
Publication Year 2021
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Natural Sciences; Physics
Temporal Coverage Begin 2018-05-14T08:00:00Z
Temporal Coverage End 2018-06-06T10:11:39Z