This dataset provides a high-resolution (10 m) pan-European map of forest Growing Stock Volume (Vol) for the year 2020, along with an accompanying standard deviation layer. It is part of the PathFinder collection of forest structure maps, which integrates Sentinel-2 satellite imagery, auxiliary geospatial layers, and National Forest Inventory (NFI) data to deliver detailed forest attribute predictions across Europe. The map supports applications in forest management, biomass estimation, carbon accounting, and ecological modeling. For methodology and data integration details, see the documentation dataset of the PathFinder collection (https://doi.org/10.18710/OEYKEG) and the following publication: Miettinen, J., Breidenbach, J. et al. (2025). PathFinder's High-Resolution Pan-European Forest Structure Maps: An Integration of Earth Observation and National Forest Inventory Data. Zenodo. https://doi.org/10.5281/zenodo.17107267.