Paleoproductivity proxies and alkenone precursors in the Western Mediterranean during the Early-Middle Pleistocene transition

DOI

Multidisciplinary analyses (taxonomic analysis of coccolithophore assemblages, stable oxygen isotopes, marine and terrestrial biomarkers) have been carried out on sediments from Ocean Drilling Program Site 975 in the Algero-Balearic basin (38°53.8′ N, 4°30.6′ E), through late marine isotope stage (MIS) 20-19 (from 800 to 756 thousand years ago). The aim of the study was to compare coccolithophore paleoproductivity proxies, such as C37 alkenone concentration (ng/g) and nannofossil accumulation rate (NAR=coccoliths * cm- 2 * kyr-1), and understand their relationship with paleoceanographic condition and paleoenvironmental changes, alkenone-producing precursors and unsaturated C37 alkenone compounds (C37:2, C37:3, C37:4).Measurements of stable oxygen isotope analysis were performed on four to fifteen specimens of Globigerina bulloides (250–315 μm). These analyses were performed on an Isoprime 100 (Elementar) dual-inlet Isotope Ratio Mass Spectrometer (Elementar) at the Laboratoire des Sciences du Climat et de l'Environnement (LSCE, France). The results are expressed as δ18O vs V-PDB (in ‰) through calibration to international NBS standards. Quantitative analyses on coccolithophores were performed at the Dipartimento di Scienze della Terra e Geoambientali, Bari University (Italy), using a polarized light microscope at 1000 X magnification, and abundances were determined by counting at least 500 coccoliths of all sizes. Nannofossil dissolution index (DI) has been calculated as follows: small gephyrocapsids/(small gephyrocapsids + Calcidiscus leptoporus). Marine and terrestrial biomarkers have been processed at the Instituto Português do Mar e da Atmosfera (Portugal). The patterns of C37 alkenone concentration and NAR provided reliable information on past paleoproductivity changes. The Alkanol Preservation Index (API) obtained by the relative proportion of n-hexacosan-1-ol (C26OH) to the sum of C26OH plus n-nonacosane (C29) [API = C26OH/(C26OH + C29)], was used as a proxy of sea bottom ventilation in the basin. Sea surface temperature (SST) was estimated calculating the alkenone Uk'37 index that is based on the di- and tri-unsaturated alkenone ratio [(C37:2)/(C37:2 + C37:3)] and converted into temperature values using the global core top calibration of annual SST [Uk'37 = (0.033*SST) + 0.044], with a methodology uncertainty of ±0.5 ◦C. Tetra-unsaturated compound (C37:4) was considered as an indicator of lower temperature and low salinity waters and linked to polar and subpolar water influx into the Western Mediterranean.

This dataset was funded by a Geoscience PhD scholarship from University of Bari, Italy.

Identifier
DOI https://doi.org/10.1594/PANGAEA.982519
Related Identifier References https://doi.org/10.1016/j.palaeo.2022.111104
Metadata Access https://ws.pangaea.de/oai/provider?verb=GetRecord&metadataPrefix=datacite4&identifier=oai:pangaea.de:doi:10.1594/PANGAEA.982519
Provenance
Creator Marino, Maria ORCID logo; Rodrigues, Teresa ORCID logo; Quivelli, Ornella; Girone, Angela ORCID logo; Maiorano, Patrizia ORCID logo; Bassinot, Franck
Publisher PANGAEA
Publication Year 2025
Rights Creative Commons Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Representation
Resource Type Bundled Publication of Datasets; Collection
Format application/zip
Size 3 datasets
Discipline Earth System Research
Spatial Coverage (4.510 LON, 38.897 LAT); Western Basin
Temporal Coverage Begin 1995-05-14T00:00:00Z
Temporal Coverage End 1995-08-19T00:00:00Z