Spin-orbit transitions of Co3+ in LaCoO3
In our first measurement of the high energy spectrum of LaCoO3 we observed a signal which is a promising candidate for an electronic transition from the low spin ground state of Co3+ to one of the excited electronic levels at 650 ± 50 meV. We propose to perform measurements with higher incident energies up to 2.5 eV to confirm that this excitation is magnetic in origin, and to search for transitions at higher energies which are predicted by a model for localized Co3+ in LaCoO3. Observation of these levels would allow us to refine a model for Co3+ and, in particular, to identify the nature of the spin state transition which occurs on warming this canonical transition metal oxide compound above about 100 K.
- 100Hz
- 1310050
- 2pi 108
- 2pi 122
- 2pi 93
- 600
- A chopper
- AND
- Boothroyd
- Co3
- Ei 1000
- Ei 1000meV
- Ei 120meV
- Ei 1250
- Ei 1500
- Ei 1750
- Ei 1750meV
- Ei 2000
- Ei 2250
- Ei 2500
- Ei 30 1meV
- Ei 3000
- Ei 3000meV
- Ewings
- LaCoO3
- MAPS
- Rot 10 5
- Rot 100 5
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- Rotter
- Spin orbit
- T 300K
- T base
- T cooling
- T warming
- T_head 100K
- T_head 150
- T_head 215K
- T_head 225K
- T_head 300
- T_head 50
- T_head base
- T_samp 220K
- WB
- alignment
- atten
- cobalt
- f 600Hz
- freq 200Hz
- freq 400Hz
- fully
- hg 48
- jaws
- lanthanum
- max
- nim 100Hz
- nimonic
- open
- oxide
- phi 10
- phi 20
- phi 35
- phi 40
- phi 60
- psi 0
- psi 1
- psi 10
- psi 11
- psi 12
- psi 13
- psi 14
- psi 15
- psi 16
- psi 17
- psi 18
- psi 19
- psi 2
- psi 20
- psi 21
- psi 22
- psi 23
- psi 24
- psi 25
- psi 26
- psi 27
- psi 28
- psi 29
- psi 3
- psi 30
- psi 31
- psi 32
- psi 33
- psi 34
- psi 35
- psi 36
- psi 37
- psi 38
- psi 39
- psi 4
- psi 40
- psi 41
- psi 42
- psi 43
- psi 44
- psi 45
- psi 46
- psi 47
- psi 48
- psi 49
- psi 5
- psi 50
- psi 51
- psi 52
- psi 53
- psi 54
- psi 55
- psi 56
- psi 57
- psi 58
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- psi 6
- psi 60
- psi 61
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- psi 7
- psi 70
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- psi 73
- psi 74
- psi 75
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- psi 8
- psi 80
- psi 81
- psi 82
- psi 83
- psi 84
- psi 85
- psi 86
- psi 87
- psi 88
- psi 89
- psi 9
- psi 90
- setup
- transitions
- vanadium
- vg 42
- wccr 8 9
Provenance | |
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Creator | Dr Martin Rotter; Dr Russell Ewings; Professor Andrew Boothroyd |
Publisher | ISIS Neutron and Muon Source |
Publication Year | 2021 |
Rights | CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/ |
OpenAccess | true |
Contact | isisdata(at)stfc.ac.uk |
Representation | |
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Resource Type | Dataset |
Discipline | Photon- and Neutron Geosciences |
Temporal Coverage Begin | 2013-05-24T09:43:08Z |
Temporal Coverage End | 2018-09-25T08:29:00Z |