GIWAXS and GISAXS studies of ion migration in mixed lead-halide perovskites

DOI

We will use GIWAXS and GISAXS to understand the structural changes in mixed halide perovskites APbX3 (A=methylammonium, formamidinium, cesium; X=Cl, Br, I). We will track the light-induced segregation of halides in I/Br and Br/Cl mixed perovskites. We will observe the formation of pure phase domains (i.e. I-rich, Br-rich or Cl-rich) and characterize their typical size and time scale over which they appear. We will study the influence of chemical composition and crystal grain size on halide migration. This information will help to improve the stability of the perovskite-based solar cells and give an insight into ion migration in perovskite structures. The samples will be prepared at ESRF using own portable spin coater which was already tested at ID10.

Identifier
DOI https://doi.org/10.15151/ESRF-ES-2113933332
Metadata Access https://icatplus.esrf.fr/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatplus.esrf.fr:inv/2113933332
Provenance
Creator Jasmin RETTENMEIER; Ekaterina KNESCHAUREK ORCID logo; Sebastian SCHWARTZKOPFF; Niels SCHEFFCZYK; Ross CARTER; Ivan ZALUZHNYY ORCID logo; Oleg KONOVALOV ORCID logo; Hans MAUSER; Paul ZIMMERMANN; Dmitrii LAPKIN; Dmitrii LAPKIN ORCID logo
Publisher ESRF (European Synchrotron Radiation Facility)
Publication Year 2028
Rights CC-BY-4.0; https://creativecommons.org/licenses/by/4.0
OpenAccess true
Representation
Resource Type Data from large facility measurement; Collection
Discipline Particles, Nuclei and Fields