Diffusive behavior in battery materials under electric field

DOI

Lithium diffusion in magnetic materials is found to be well detected by muon-spin spectroscopy. However, such a diffusive behavior has been measured without potential gradient, resulting in leading a self-diffusion coefficient. On the other hand, electrochemical measurements are always carried out under potential gradient and provide a chemical-diffusion coefficient. Although a chemical-diffusion coefficient is proportional to a self-diffusion coefficient, a proportional factor, i.e. a thermodynamic factor is not clearly determined by conventional measurements. Thanks to the time structure of the pulsed muon-beam, we could apply pulsed electric field to the sample just before muons come. This means that a chemical-diffusion coefficient would be estimated by muSR measurements under pulsed electric field. We thus wish to propose the experiment on battery materials under electric field.

Identifier
DOI https://doi.org/10.5286/ISIS.E.24088950
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/24088950
Provenance
Creator Dr Jun Sugiyama; Professor Martin Mansson; Dr Masashi Harada; Dr Hiroshi Nozaki; Dr Izumi Umegaki
Publisher ISIS Neutron and Muon Source
Publication Year 2015
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Photon- and Neutron Geosciences
Temporal Coverage Begin 2012-05-24T17:33:00Z
Temporal Coverage End 2012-08-03T08:36:53Z