Zr-based metal-organic frameworks as carbon-free energy carriers: a study of their structural interactions with ammonia

DOI

Structural information of Zr-based MOFs including UiO-67, m-UiO-67, and UiO-bpydc upon ammonia loading will be investigated by an in situ neutron powder diffraction technique. Rietveld refinement will be conducted to elucidate adsorption geometries and locations of ammonia in this MOF-guest system, enabling an understanding of the exceptional ammonia uptake and the unusual adsorption behaviours of m-UiO-67 and UiO-bpydc. This work will lead to an improved ammonia storage and a more rational design for catalytic ammonia decomposition.

Identifier
DOI https://doi.org/10.5286/ISIS.E.101138223
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/101138223
Provenance
Creator Ms Kirsty Purchase; Professor Yufei Zhao; Mr Yiyang Li; Mr Chris Foo; Miss TATCHAMAPAN YOSKAMTORN; Professor Edman Tsang; Dr Pu Zhao; Dr Fabio Orlandi
Publisher ISIS Neutron and Muon Source
Publication Year 2022
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Chemistry; Natural Sciences
Temporal Coverage Begin 2019-02-28T08:00:00Z
Temporal Coverage End 2019-03-02T10:16:44Z