Solvent-Controlled Quadruple Catenation of Giant Chiral [8+12] Salicylimine Cubes Driven by Weak Hydrogen Bonding [Data]

DOI

A quadruply interlocked catenane has been formed from giant chiral [8+12] salicylimine cubes in a reaction that can be controlled by the reaction solvent. Single-crystal X-ray diffraction revealed hydrogen bonding to be a central driving force for the catenation. Furthermore, scrambling experiments with partially deuterated cages allowed mechanistic insights into the interlocking process.

Identifier
DOI https://doi.org/10.11588/data/TIYBD2
Related Identifier https://doi.org/10.1002/anie.202217251
Metadata Access https://heidata.uni-heidelberg.de/oai?verb=GetRecord&metadataPrefix=oai_datacite&identifier=doi:10.11588/data/TIYBD2
Provenance
Creator Wagner, Philippe; Rominger, Frank; Gross, Jürgen H.; Mastalerz, Michael
Publisher heiDATA
Contributor Mastalerz, Michael
Publication Year 2023
Rights CC BY 4.0; info:eu-repo/semantics/openAccess; http://creativecommons.org/licenses/by/4.0
OpenAccess true
Contact Mastalerz, Michael (Institute of Organic Chemistry, Ruprecht-Karls-Universität Heidelberg)
Representation
Resource Type Dataset
Format application/zip
Size 24860964; 19659578; 121578735; 8065078; 6614423; 19264576; 134034620; 19490362; 18481644; 18582664; 70779498; 91787622; 70748809; 14036151; 61493583; 8052578; 3472986
Version 1.0
Discipline Chemistry; Natural Sciences