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Structural study of oxygen ion conduction in microporous Mayenite
The crystal unit cell of mayenite, 12CaO.7Al2O3, consists of a cubic lattice of [Ca24Al28O64]4+ with the remaining 2*O2- contained in cages, which are linked by channels within... -
4f electronic states of the filled skutterudite compound PrFe4Sb12 synthesize...
Crystals of the filled skutterudite PrFe4Sb12 with the 73~87% Pr-site filling fractions prepared under ambient pressure show some magnetic ordering around 5 K and their... -
Muon Spin Relaxation studies of Ni2TCNQ, Ni(TCNQ)2 and related materials
Amorphous molecular magnetic materials Ni2(OA) (OA:organic acceptor) were reported to exhibit ferromagnetism with Curie temperatures >400K. This work is controversial as it... -
Stochastic vs. Intermolecular Motions in Strongly Associated Liquids: The Cas...
Neutron scattering is a powerful technique to study stochastic motions in liquids but it requires an energy resolution well below the meV range. As a consequence, quasielastic... -
Investigation of giant crystal electric field (CEF) splitting in CeIr3Si2
CeIr3Si2 exhibits highly anisotropic bulk properties with two magnetic transitions at TN1 ~ 3.9 K and TN2 ~ 3.1 K. The overall CEF splitting of the J=5/2 ground multiplet of... -
Excitations, BEC, and partially ordered states of liquid 4He in disorder
We propose measurements of the elementary phonon-roton (p-r) excitations of liquid 4He confined in porous MCM-41 (45 Å pore diameter) at wave vectors Q ¿ beyond the roton¿, 2.4... -
Magnetic excitations in mesoporous hematite
We have recently prepared mesoporous forms of various metals oxides. In some cases the imposition of a mesostructure changes other properties of the material significantly. One... -
The mechanism of Oxygen Absorption/Desorption in YBaCo4O7+d (Y114) studied by...
An uncommon oxygen absorption/desorption behavior for cobalt oxide YBaCo4O7+d was found[Karppinen et al. Chem Mater 18 2006 490]. Y114 absorbs and desorbs oxygen up to d = 1.5... -
Pressure-dependence of the anisotropic exchange interactions in two closely r...
There are no magneto-structural correlations for clusters containing transition metal ions with non-zero orbital angular momentum in the ground state. Octahedrally coordinated... -
Muon spin relaxation studies of KTCNQ and related compounds
Potassium tetracyanoquinodimenthane (KTCNQ) undergoes a spin-Peierls (SP) transition at 396K where a transformation from uniform to dimerised TCNQ- molecules in 1D columns... -
Correlation of structure and magnetic ordering with composition in layered co...
We propose to use HRPD to determine the detailed structures of a series of cobalt oxysulfides containing Co in square planar coordination. Two compositions Sr2CoO2Cu2-deltaS2... -
Diffraction Resistance Measurements of a Chalcopyrite
During the course of a PhD project funded by CCLRC's CMPC, we have developed a cell that allows electrical transport property measurements to be made simultaneously with the... -
Quasielastic scattering in stuffed spin ices: defects or low lying singlets?
The subjects of this proposal, Ho2+xTi2-xO7-x/2, are brand new materials1 related to Ho2Ti2O7, a spin ice2,3. They have the remarkable property of remaining disordered at very... -
Correlation of structure and magnetic ordering with composition in layered co...
We propose to use OSIRIS to determine the magnetic structures of a series of cobalt oxysulfides containing Co in square planar coordination. Several compositions... -
The Influence of Post-Quench Delay on the Residual Stresses in Cold Compresse...
Residual stresses introduced into large aerospace aluminium components after the queching procedure carried out to form the desired microstructure can result in large, costly... -
Sustainable polymeric deposition aids
This is a new programme of work and a collaboration between CCLRC, Oxford, Unilever and Manchester. It is concerned with polymer aided deposition to solid substrates, using... -
Phase Behaviour in Pyrazine and Tetramethylpyrazine.
Pyrazine-I is stable < 302 K, phase II exists from 302-310 K, and phase III from 310-324 K. The known phase-I forms an ordered structure. It is thought that structures of... -
A SANS Study on the Influence of Shear on Peptide Fibrillisation
Time-resolved SANS will be performed to investigate the effect of shear on the fibrillisation of insulin following denaturation. The rheological response will be measured... -
The elusive ¿cubic¿ phase of BiFeO3 and related materials
We wish to probe the suggested existence of a high-temperature cubic perovskite phase in the multiferroic material BiFe0.7Mn0.3O3. The parent phase of this material, BiFeO3, was... -
Neutron Powder Diffraction Experiments on Ternary Alkali Metal Palladium and ...
Na2PdC2 and Na2PtC2 are the first examples of ternary alkali metal transition metal acetylides. They were synthesized and structurally characterised by our group in 2001 based...