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INS Study of Nb2O5-supported Pt, Pd and Ru catalysts for the Efficient Lignin...
We request 9 days on TOSCA to carry out INS study of the hydrogenolysis of 4-methylphenol on Pt, Pd and Ru-loaded Nb2O5 catalysts for lignin conversion. This proposed study will... -
Kinetics of Benzene Hydrogenation Revisited in the Presence of Excess Liquid
Heterogeneous catalysis, where the reagents are either contained in a liquid medium, or are liquids in their own right, plays a significant part of the chemical industry. These... -
Determination of a reaction area of cathode in a liquid electrolyte by muSR
In order to estimate a reliable reaction area (a_r) between cathode and liquid electrolyte in a Li-ion battery, we wish to propose a muSR experiment on a charged-state cathode... -
Structural determination of non-stoichiomentric phases Li2+yND for 0<y<1
In a series of in situ neutron diffraction measurements from deuterium up-take in Li3N, the present authors have identified a novel non-stoichiometric 'quasi-imide' of... -
Decomposition studies of Li(1-x)NaxND2, LiNa2(ND2)3 and Li3Na(ND2)4
We ask for 3 days on GEM to study in-situ the decomposition of the Na-substituted LiNH2 phases, Li1-xNaxND2, LiNa2(ND2)3, Li3Na(ND2)4 and their reactions with LiD. LiNH2 is the... -
An abiotic analogue of methane monooxygenase for the catalytic oxidation of h...
We request 3 days Direct Access on TOSCA to complete the INS measurements of our previous experiment 1610254. We want to characterise the vibrational signatures of a new... -
Szilard-Chalmers reaction: towards understanding of breaking of chemical bond...
When a nucleus captures a low energy neutron it emits a gamma ray as it recoils. The recoil energy is often sufficient to break a covalent bond to the atom concerned. The effect... -
Probing the structure of antibiotic-gold nanoparticle conjugates
In a one-pot synthesis, we are able to produce spherical gold nanoparticles capped with antibiotics, without the use of other chemicals by using the antibiotic as the reducing... -
Penetration and reaction of hydroxyl radical into organic films at the air-wa...
The Earth¿s climate is strongly influenced by clouds. The oxidative processing of pollutants in clouds affects droplet size and optical properties, important climatic effects.... -
Copy of: IINS Study of the Molecular Properties of Hydrogen Peroxide/Water Mi...
Hydrogen Peroxide is one of the cleanest, most versatile strategic base chemicals available. It is used at the large scale as oxidising agent in the chemical industry, as a... -
HD dynamics in filled ices prepared between 3 and 7 kbar
The proposing team has recently obtained important neutron scattering results on samples containing molecular hydrogen (sII and sH hydrogen-filled clathrate hydrates), measured... -
The first in operando INS study of a catalytic reaction: CO oxidation over PdO
Inelastic neutron scattering has been used to study adsorbed species on catalysts for more than 30 years. All of this work has one feature in common: they are all ¿snapshots¿ of... -
Impact of surfactant interactions on fate of marine aerosols: NO3-initiated o...
Mixed films of palmitic acid (PA) and galactocerebrosides (GCB) a proxy for marine aerosol exhibit attractive interactions due to H-bonding of galactose and carbonyl head... -
Study of the reaction mehanism for carbon-based FeF3 nanocomposites as cathod...
Metal fluoride materials, through the use nanocomposites, recently appear as potential candidates as next generation high energy density positive electrodes for Li-ion... -
The use of INS to investigate reactions relevant to Fischer-Tropsch catalysis
In collaboration with an industrial partner, the PI is seeking to use INS to help characterise a series of catalysts active for the important Fischer-Tropsch (F-T) process. As... -
Hydrogenation of Benzene followed by Total Scattering and in situ 13C NMR
Catalysis is defined as the increase of the rate of the reaction or directing the reaction to one of the thermodynamically permitted pathways that lead to different products. It... -
Investigation of the phases formed during the conversion reaction of the C-ba...
FeF2 is a conversion reaction material that undergoes a reaction with lithium: FeF2+2Li++2e-<->2LiF+Fe, which results in a high theoretical capacity, 571 mA/g.... -
Probing the products of free radical reactions in ionic liquids
Many room temperature ionic liquids (salts with melting points near room temperature that hereafter will be referred to as ionic liquids) are ¿green solvents¿ for chemical... -
Transition metal carbides via novel, ultrafast microwave synthesis; Reaction ...
We are investigating the ultra-rapid synthesis of transition metal carbides using microwave (MW) irradiation. Currently we are establishing an understanding of these reactions... -
Vibrational Spectroscopic Analysis of NbOPO4Hx and Ru/NbOPO4Hx catalysts for ...
Lignin valorization is receiving increasing attention. We request 7 days on TOSCA to carry out inelastic neutron scattering (INS) study of two key chemical processes in lignin...