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Revising the onset of anharmonicity in proteins
Our previous INS studies of ¿dry¿/hydrated apoferritin show that the hydrated protein undergoes a dynamical transition, Td, at 200K. Such behavior, first modeled by Doster et al... -
Structural study of oxygen ion conduction in microporous Mayenite
The crystal unit cell of mayenite, 12CaO.7Al2O3, consists of a cubic lattice of [Ca24Al28O64]4+ with the remaining 2*O2- contained in cages, which are linked by channels within... -
Magnetic Properties of Rare-Earth Carbonates
We have prepared a new family of rare-earth carbonates, R4(CO3)6(H2O)2en (R=Dy-Lu). With the exception of R=Er, all materials exhibit a steadily decreasing meff below 70K. The... -
The Interaction of Ammonia with Binary and Ternary Deuterides;
The interaction of ammonia with binary hydrides (prototypically, the interaction of LiH with ammonia gas) is thought to be the predominant interaction for hydrogen production... -
Neutron scattering study on dynamics of cytochrome c in MCM41
Studies of internal dynamics in the pico seconds timescale, of cyt c trapped in MCM-41, would allow the forms, geometry, amplitudes and time-dependence of the motions involved... -
Decomposition studies of Li(1-x)NaxND2, LiNa2(ND2)3 and Li3Na(ND2)4
We ask for 3 days on GEM to study in-situ the decomposition of the Na-substituted LiNH2 phases, Li1-xNaxND2, LiNa2(ND2)3, Li3Na(ND2)4 and their reactions with LiD. LiNH2 is the... -
Simultaneous INS and Raman studies of lysozyme
The proposers have obtained a dispersive Raman spectrometer that is fibre optically coupled to a custom centrestick that will allow simultaneous Raman and neutron measurements.... -
Water-based gels of half N-acetylated chitosans; potential pharmaceutical exc...
These experiments are part of a much broader programme at the University of Reading. focused on the use of water-soluble half-acetylated chitosan as a mucoadhesive polymer,... -
Inelastic neutron scattering in the Ce3Co4Sn13 heavy Fermion compound
We propose to use the OSIRIS spectrometer to measure the inelastic magnetic scattering on the newly discovered heavy Fermion compound Ce3Co4Sn13. This compound has one of the... -
Towards an accurate structural phase diagram for the novel BiScO3-PbTiO3 ferr...
The aim of this experiment is to determine accurately the crystal structures of phases in the (1-x)BiScO3-xPbTiO3 (BST-PT) perovskite phase diagram, particularly in the vicinity... -
Mechanical twinning in quartz rocks: in situ experiments at stress and during...
Previous experiments at ENGIN-X (Wenk et al. 2007) established that quartz rocks undergo mechanical twinning if stressed above 100 MPa. The amount of twinning is highly... -
Mesostructured titania films from ethanolic solutions
In this proposal we wish to continue our current work on mesostructured inorganic films in largely ethanolic solutions, containing limited amounts of water. Transition metal... -
O/N-distribution in host lattices for rare-earth doped phosphors in light emi...
Nitridosilicates and oxonitridosilicates (sions) gain more and more importance as host lattices for rare-earth doped phosphors in light emitting diodes. By means of... -
Powder diffraction studies under high deuterium pressure
The aims of the experiment are (1) to obtain structural data for the model hydrogen storage intermetallic LaNi5 under a deuterium pressure of 3000 bar at cryogenic temperatures,... -
Co-surfactancy of oil-soluble and water-soluble surfactants in emulsion stabi...
The structures of emulsions formed from mixed oil-soluble and water-soluble amphiphiles (respectively derivatives of polyisobutylene, PIBSA, and polyacrylamide, PAM) will be... -
Search for magnetic ordering in the high pressure metallic state of LuNiO3 & ...
It has very recently been shown that Mott-insulators located at the crossover regime closer to the itinerant side, such as RNiO3, undergo a pressure-induced transition into a... -
The Influence of Post-Quench Delay on the Residual Stresses in Cold Compresse...
Residual stresses introduced into large aerospace aluminium components after the queching procedure carried out to form the desired microstructure can result in large, costly... -
Low temperarature structure of Sr2CoO2Cu1.85S2
This proposal aims to exploit the superior flux on the upgraded HRPD coupled with the intrinsic high resolution to examine the differences between a sample of Sr2CoO2Cu1.85S2... -
RF decoupling of the F-mu-F state
NMR has become an extremely sophisticated experimental technique because of the use of pulse sequences which allow the control and manipulation of a nuclear spin system or... -
Investigation of the impact of mechanical twinning on the thermal expansion b...
We request three days of beam-time on POLARIS to investigate the influence of thermally-induced twinning on the thermal expansion behaviour of polycrystalline calcite....