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Structural investigation of the high temperature phases in ammonium iodate
We will investigate the structures of the high temperature (RT to 400K) phases of ammonium iodate, and the features that accompany these phase transitions. From our previous... -
In-situ reaction of lithium amide or imide with manganese(IV) oxide
We request 3 days beam time on POLARIS for in-situ powder diffraction studies of the reactions of lithium amide or lithium imide with manganese(IV) oxide under flowing argon or... -
Molecular Dynamics in Polymer Nanocomposites
Our aim is to determine whether the fast dynamics, of either the backbone or the phenyl ring of polystyrene, are altered by the presence of carbon nanotubes, and, if so, whether... -
Hydrogen from ammonia using lithium imide metal nitride composites
Light metal amides and imides are a new class of highly active ammonia decomposition catalysts. Indeed, composites of lithium imide and transition metal nitrides are likely to... -
Magnetic ordering in the layered oxide chalcogenides A2FeO3CuCh (A = Ca, Sr; ...
This proposal is to measure the evolution of the magnetic structures of a series of iron oxide chalcogenides and compare the structures as a function of cation sizes and with... -
Molecular motions in novel water-soluble organometallic gels
The aim of this proposal is to study the internal dynamics of a novel organometallic polymers based on two metal-containing moieties -Ru, Au- bridged through a tridentate... -
In-situ neutron powder diffraction studies of non-stoichiometry in Na battery...
We request 3 days on POLARIS to study the detailed crystal structure of a sodium battery cathode material that is currently under consideration for use in commercial sodium... -
Na-ion diffusion mechanisms in NaxFe1/2Mn1/2O2 cathode materials
NaxFe1/2Mn1/2O2 has been identified as a potential cathode material for Na-ion batteries since it has comparable electrochemical performance to commercially available Li-ion... -
Monomer dynamics in polymer nanocomposites
We have recently shown that the addition of single walled carbon nanotubes produces a minimum in the diffusion coefficient with increasing nanoparticle concentration. Initially,... -
Solvent-solute interations in PET recycling systems
Glycolysis of polyethylterephthalate (PET) catalysed by ionic liquid solvents could offer a metal-free low cost approach to chemical recycling of waste PET. This work will... -
Neutron diffraction study of antiperovskite Mn3CoXN: a potential magnetocalor...
Materials exhibiting giant magnetocaloric effect (i.e. the large temperature change under a magnetic field variation) are the most promising type for magnetic refrigeration.... -
Monomer dynamics in polymer nanocomposites
We have recently shown that the addition of single walled carbon nanotubes produces a minimum in the diffusion coefficient with increasing nanoparticle concentration. Initially,... -
High resolution neutron powder diffraction on Ni-Mn-Sn based shape memory all...
The composition Ni2.04Mn1.4Sn0.56 belongs to the group of metamagnetic shape memory alloys and it shows multiple magnetic phases as a function of temperature. In a recent muon... -
Probing atomic and mesoscale structural correlations in 1-alkyl-3-methylimida...
This proposal aims to extend our understanding of ionic liquid structure by performing measurements that will complement the data previousy collected on SANDALS. We propose to... -
Why is Choline Arginate the Best Performing Bio-IL for Biomass Pretreatment?
The ionic liquid choline arginate [Ch][Arg] is more effective for coal pretreatment than other choline based amino acid ILs, but the underlying mechanism is unclear.... -
Molecular weight dependence of 2D-confined dynamics in glass-forming systems
We seek to explore the dynamics of glass forming systems upon extreme 2D-confinement. These experiments are motivated by preliminary experiments on oligomers and macromolecules... -
Electrostatic interaction effects in orientationally disordered phases
Plastic phases are characterized by a positional ordering of the molecular centers of mass while molecules are rotating in a hindered way. Therefore these phases are... -
Structural Insights into Borohydride-Halide Li-Ion Conductors, LiM(BH4)X (X= ...
Solid state electrolytes are key components to replace volatile liquid electrolytes in lithium-based batteries to deal with the safety concern. We propose here variable... -
PROTON DYNAMICS IN ALKYLAMMONIUM NITRATE IONIC LIQUIDS
Ionic liquids are of interest to chemistry and material sciences because of their designer properties. Protonated ionic liquids are excellent proton carriers in fuel cell... -
Hydrogen production from ammonia using lithium imide: an isotope study
We have recently discovered that light metal amides and imides are excellent cattalysts for the decomposition of ammonia. We request 3 days on POLARIS to perform in situ neutron...