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Cation environments in lead-free glasses
BaO+ZnO containing glasses are being studied as an alternative to lead-based glasses because they exhibit excellent dielectric, thermal, optical and crystallisation properties.... -
Structures of New Oxides from Total Scattering
Our objective is to determine accurate structural models for some novel oxide materials that we have recently prepared using new synthesis approaches, each of which is formed as... -
Disorder in substituted beta-tricalcium phosphate for waste immobilisation
We have a long established interest in the materials used for the immobilisation of nuclear waste from the domestic power industry and legacy waste from various defence... -
Structural investigation of biodegradable Mg-based bulk metallic glass
Mg-Zn-Ca glasses show considerable promise for use as medical implants. Magnesium, zinc and calcium are all elements found within the human body, and the biocompatibility of... -
As2Ch3 glasses: Understanding the relationship between glass structure and no...
We wish to study a series of glasses of composition As2Ch3 (Ch = S, Se and Te) to investigate the effect of varying the chalcogen type on the non-linear optical (NLO) behaviour... -
Structural Studies of High Level Waste Glass
The aim of this proposal is to develop a methodology to investigate multicomponent glass structure, combining neutron diffraction, XRD, NMR, ab initio MD, and RMC. We wish to... -
The effect of combined modifiers: understanding the interactions between alka...
The mixed alkali effect is a well-known phenomenon whereby combining two alkalis in a ternary glass system can produce physical properties which can be superior to, but cannot... -
Chemical disorder and network structure of glassy As2Te3
Telluride glassy systems are widely used for phase-change optical recording. They are also promising materials for far-IR applications. The atomic structure of telluride glasses... -
Unraveling the crystal structure of cuprice, CuOH×H2O GEM
Long-term nuclear waste repository strategies in Europe include the developing of safe multi-barrier isolation of spent nuclear fuel. One of the considered schemes is the... -
Structural role of magnesium in aluminosilicate glass
A combination of high real-space resolution neutron diffraction and 27Al and 29Si NMR experiments will be used to measure the structure of glassy MgO-Al2O3-SiO2. A focus will be... -
New insight on bismuthate glass networks
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The First Structural Characterisation of some Gallium Oxide Polymorphs
We propose to make the first detailed structural study of some polymorphs of gallium oxide that remain poorly characterised and yet have applications in catalysis and are used... -
Structure of Lead Germanate Glasses
We wish to perform a detailed and comprehensive study of the structure of lead germanate glasses, over a wide range in composition. Most structural studies of germanate glasses... -
Structural origins of the high sulphur solubility of barium rich glasses
We will investigate the structural origin of the high sulphate solubility of Ba-rich silicate glasses with radioactive waste immobilisation applications by measuring total... -
Investigating the local structure of sodium within Bioglass®.
Bioactive glasses are of considerable interest due to their potential for biomedical applications. In order to model the behaviour and dissolution of these materials it is... -
Structure of niobium phosphate glasses
Niobium is one of the candidates for causing strong non-linear optical properties in oxide glasses. Recently, Raman gain experiments on niobium phosphate glasses were quite... -
Developing a model for tellurium coordination change in glasses
We wish to better understand the evolution of the tellurium environment in glasses with the addition of modifier oxides. The aim is to relate these structural changes to the... -
Null Isotope Study of Lithium Borogermanate Glasses - continuation
Alkali borogermanate glasses are topologically complex, in that [BOn] (n = 3, 4)and [GeOn] (n = 4, 5, 6) polyhedra can coexist. Equilibrium between these structural units has... -
A Structural Study of Alkaline-Earth Tellurite Glasses.
We wish to better understand the interaction between the alkaline earth modifiers and the tellurite glass network. The aim is to relate structural changes in the glasses with... -
Structural studies of modified iron phosphate glasses to understand key struc...
We intend to use neutron diffraction and x-ray diffraction to investigate the structure of potassium and barium iron phosphate glasses, which are potential candidate systems for...