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The Effect of Temperature on Liquid 1-Methylnaphthalene Structure: An Integra...
We are studying asphaltene behavior in multiple solvent environments to investigate the key motives behind polyaromatic hydrocarbon self-aggregation. We have found that 1-... -
Modes of pi-stacking in neat and aqueous solutions of 1-naphthyl-3-methylimid...
The proposed work continues our investigations of the structure, aggregation, self-assembly and ion pairing of ionic liquids in the neat state, at interfaces, and in solutions.... -
Model Amphiphilic Deep Eutectic Liquids
Deep eutectic liquids (DELs) - mixtures of high melting-point solids that form stable liquids near room temperature ¿ have recently emerged as a new class of novel solvents with... -
Local and long-range ordering in concentrated nanotube solutions
Manipulating nanoparticles in liquids is crucial for their scalable implementation in future technologies. For example, such liquids can be used like paint to create uniform... -
Growth of Nanostructured Ceria in Choline Chloride:Urea-Water Deep Eutectic S...
In our recent work we have studied formation of nanostructured cerium oxides from the choline chloride:urea deep eutectic solvent (DES). We found that the nanostructure of the... -
Role of DMSO in Ionic Liquid / DMSO Mixtures
This proposal aims to study the interactions within a prototypical ionic liquid / co-solvent system. Such systems are currently under investigation as potential solvating media... -
Local and long-range ordering in concentrated nanotube solutions
Manipulating nanoparticles in liquids is crucial for their scalable implementation in future technologies. For example, such liquids can be used like paint to create uniform... -
Alcohols in Cationic Surfactant Micelle Solutions
This proposal continues our studies of water and small molecule binding around surfactant micelles using NIMROD, to obtain previously inaccessible details of their molecular... -
Probing the Kinetics and Liquid Structure of Toluene Hydrogenation by Pt/MCM-41
In a proof-of-concept beamtime award (RB1220486) we studied the process of platinum-catalysed benzene hydrogenation in the pores of MCM-41 using standard neutron diffraction... -
Ion Binding in Tetradecyltrimethylammonium Surfactant Micelle Solutions
This proposal continues our studies of surfactant micelles using NIMROD, to obtain previously inaccessible details of headgroup-ion interactions. In our previous experiments... -
Spatial, Chemical, and Temporal Resolution of Platinum-Catalysed Benzene Conv...
This proposal aims to study the potential for neutron diffraction to offer spatially-, chemically-, and temporally-resolved information on a dynamic system, in this case the... -
Structural behavior of subcritical and supercritical carbon dioxide confined ...
Shale is an increasingly important source of natural gas and potential candidate for carbon dioxide sequestration. Understanding the gas adsorption behavior on shales is of key... -
Multiscale time-resolving study of solid state crystallisation from the mesom...
We will exploit the unique capability of Nimrod in the study of the long standing issue of polymer crystallisation. We focus on isotactic polypropylene which has been quenched... -
Investigation of Graphitic Carbon Nitride (g-C3N4) structure
Production of hydrogen from water via visible light driven photocatalytic water splitting is a future technology that may offer important routes to clean fuels. Graphitic carbon... -
The structural role of hydrogen and other guest atoms in graphitic carbon nit...
Carbon nitrides are emerging as an important class of materials with applications that range from Li+ ion and electronic charge storage in batteries and supercapacitors,... -
Cononsolvency of Poly(N,N-Diethyl Acrylamide) (PDEA) in water/ethanol mixture...
Cononsolvency is a rare phenomenon that the solubility of a polymer decreases or even vanishes in the mixture of good solvents [Macromolecules 1991, 24, 948]. Although PDEA is... -
Spontaneous solvation of graphene from KC24(NH3) and KC8 graphite intercalati...
Liquid phase exfoliation of graphite is a scalable method for the production of graphene with an inbuilt medium for the manipulation of the graphene into applications. Much like... -
Study of Deep Eutectic Solvents dilutions: nanometer size domains and molecul...
Carbon materials with nanopore structures are of great importance for development of energy storage and gas adsorption devices. The critical parameter is pore size and it is... -
Structure of Petroleum Asphaltenes in Solution
Asphaltenes are the heaviest end of crude oil and are responsible for a multitude of engineering challenges. They can precipitate from the oil, depositing, blocking pipelines... -
Understanding Amphiphilic Self-Assembly in and by Protic Ionic Liquids
The goal of this project is to understand the intermolecular forces that promote amphiphile self assembly in ethylammonium nitrate (EAN), a room temperature ionic liquid (IL)....
