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Programme Access Rosseinsky
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High Pressure studies of BiMO3 perovskites
Bismuth based perovskites have been shown display many interesting properties. The field of A site bismuth perovskites gained renewed vigour due to the recent demonstration of... -
High-pressure neutron diffraction studies of valence transitions in ACu3Fe4O12
Two new A-site ordered perovskite structure oxides, CaCu3Fe4O12 and LaCu3Fe4O12, were recently synthesized under high-pressure and high-temperature conditions in Kyoto. These... -
Thermal equations of state for kyanite, andalusite and sillimanite
The three Al-silicate polymorphs, kyanite, andalusite and sillimanite, are well-known geological markers used to determine the extent of P- and T-induced metamorphism... -
Structural study of BiNiO3 at high pressures and low temperatures
BiNiO3, synthesized at high pressure, has the unusual charge distribution Bi3+0.5Bi5+0.5Ni2+O3 with ordering of Bi3+ and Bi5+ charges on the A sites of a highly distorted... -
Understanding the "post-perovskite" structure (II): the Behaviour of CaPtO3 a...
Recently, our view of the Earth¿s lower mantle changed dramatically. It had been thought that two major phases were present throughout all of the lower mantle:... -
Search for magnetic ordering in the high pressure metallic state of LuNiO3 & ...
It has very recently been shown that Mott-insulators located at the crossover regime closer to the itinerant side, such as RNiO3, undergo a pressure-induced transition into a... -
Non-uniform elastic deformation of layered crystal structures
The experiment will resolve a discrepancy between earlier experiments carried out very recently by us and work elsewhere on the hydrostatic compression of a series of 211... -
Network compression and pressure-induced amorphisation in Zn(CN)2
Zn(CN)2 is an important material because it shows isotropic NTE over a large temperature range and to an extent more than double that of ZrW2O8. This unusual behaviour... -
High pressure effects on Jahn-Teller distortion in metal-formate perovskites
The family of guanidinium metal formates has the perovskite structure and, like many perovskites, is of interest for these materials¿ magnetic and electric properties, in...