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Investigation of the magnetic phases of the charge transfer compound CuTCNQ
The charge transfer compound CuTCNQ (TCNQ = 7,7,8,8-Tetracyanoquinodimethane) exhibits switching between two electrical resistance states when subject to an electric field. It... -
Homogeneous nucleation in phosphate-based glassy precursors to fast-ion condu...
The structure of the phosphate materials Na_{1+x}Ge_{2-x}Al_x(PO_4)_3 with x = 0, 0.4 and 0.8 will be investigated using high real-space resolution neutron diffraction. In the... -
Surveying Hebel-Slichter peaks in conventional-ish superconductors
The presence of a Hebel-Slichter peak in NMR or µSR measurements just below the critical temperature of superconductors is taken to be strong evidence for conventional behaviour... -
µSR study of mixed intercalated phases NaxLi6-xC60
Alkali-cluster intercalated fullerides (LixC60, NaxC60) proved to be suitable materials for solid state hydrogen storage. In these compounds the hydrogen is chemically absorbed... -
Unusual polymorphism in sodalites
We have recently observed extraordinary polymorphism on cooling various sodalites under vacuum. Materials undergo a phase transition followed by a fully reversible... -
Magnetic properties of graphene
Magnetic properties of graphitic compounds are of current interest for both theoretical and experimental research in the fields of condensed matter physics and magnetism. In the... -
Characterization of local symmetry breaking in superconducting La2-xBaxCuO4 &...
The mechanism of high temperature superconductivity (HTSC) remains unresolved. Of particular interest is the origin of the mysterious pseudogap (PG, a partial gap in the... -
Magnetic structures of antiferromagnetic heavy fermion CeAuAl3 and CeCuAl3 co...
CeAuAl3 and CeCuAl3 compounds crystallize in the tetragonal I4mm, BaNiSn3-type and display interesting bulk properties. Here we propose to investigate the magnetic structures of... -
Local magnetism, magnetic fluctuations and disorder, and lattice distortions ...
We aim at performing temperature (2-300K) and magnetic field (0-5T) dependent muon SR on a 1X1 cm2 mosaic, made of 4* 5x5x2 mm3 TbMn0.98Fe0.02O3 single crystals (largest area... -
Unpicking the signal of partial order from thermal motion in diffuse scatteri...
Orientationally-disordered water molecules in ice adopt a degree of partial order upon cooling, a process that is halted by kinetics at ~100 K in pure ice and ~60 K in KOH-doped... -
Crystal structure of a new hexagonal layered cobaltate LaBaCoO4+y
We have synthesized a new cobalte oxide compound. We know from preliminary measurements that its crystal structure is hexagonal, and that the magnetic behaviour is intriguing.... -
The structure of ammonia borane in ammonia and THF
In this proposal we aim to understand the solvation of AB by two of the most important solvents ? ammonia and THF. Neutron diffraction is a key technique in this context because... -
A muSR Investigation of the Magnetic Ground State and Spin Dynamics in the Tr...
In a typical magnetic material the interactions between neighbouring magnetic moments will tend to lead to their ordered alignment throughout the entire structure as it is... -
Test experiment: Neutron diffraction on helium in silica
We request 3 days of beamtime on GEM to attempt to perform neutron diffraction on helium inside vitreous SiO2. Significant amounts of helium can be dissolved into the glass... -
Structural studies of the KSbO3-type osmates Sr6Os6O19 and Bi3Os3O11
Osmium-based oxides show a wide range of interesting properties due to the variety of oxidation states osmium can adopt combined with 5d electrons displaying strong spin-orbit... -
Topotactically reduced phases containing square planar Co(II) centres
The topotactic reduction of Sr3Co2O5Cl2 and Sr3Co2O5.80 yields the Co(II) phases Sr3Co2O4Cl2 and Sr3Co2O5 respectively. These phases contain corner linked arrays of... -
Principal Component Analysis of Phase Behaviour on the Upgraded TOSCA
Principal Component Analysis (PCA) is a powerful chemometric tool for the analysis of multivariate datasets. Capitalising from the recent upgrade of the TOSCA spectrometer, we... -
Understanding Molecular Host-Guest Interactions in Functionalised Metal-Organ...
We aim to perform inelastic neutron scattering (INS) measurements at the TOSCA spectrometer to study the vibrational behaviour of designer Guest@MOF composite systems (e.g.... -
Micropore Collapse in Bulk Amorphous Solid Water
We propose to study the influence of deposition rates and annealing effects on microporous amorphous solid water samples (ASW) using NIMROD. The data will allow us to monitor... -
Influence of structure on the enigmatic thermal properties of a new layered o...
Thermoelectric (TE) materials are set to play an increasingly important role in the development of new energy efficient technologies by generating electrical current from waste...