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A total scattering study of the concentration and temperature dependence of s...
Lithium-ion batteries (LIBs) are ubiquitous in our portable electronics, however they are ill suited for applications where cost or sustainability are of paramount importance,... -
When like-charged ions attract: Size and distribution of cationic clusters in...
Contrary to the strong electrostatic repulsion between like charged ions, last year the Ludwig group, used IR and NMR spectroscopy combined with computational methods, to reveal... -
Solvation of sodium by glyme-based electrolytes for sodium intercalation into...
Here we propose to study the local structure of sodium ion in glyme electrolytes for sodium ion batteries. Glyme electrolyte are linear ethers of the structure... -
Specific ion effects in molecular non-aqueous electrolytes
Specific-ion (Hofmeister effects) are ubiquitous whenever ions are dissolved in solution and are important in many research fields from chemistry, to biology and in materials... -
Synthetic Ion Channels Formed By Self-Assembly of Crown Ethers
Ion channels are present in cell membranes and permit the transport of ions across from the cell interior to the cell exterior (or vice versa), and hence allow chemical and... -
Solvent-solute interations in PET recycling systems
Glycolysis of polyethylterephthalate (PET) catalysed by ionic liquid solvents could offer a metal-free low cost approach to chemical recycling of waste PET. This work will... -
Linking the solid state and solution thorium aqua structures: solution struct...
A understanding of the aqueous chemistry of the actinide ions is not as well developed as for transition metals or the lanthanides. Fundamentally important information such as... -
Frustrated Lewis pairs: encounter complexes in an ionic liquid
Frustrated Lewis Pairs (FLPs) are combinations of bulky Lewis acids and bases, which cannot form acid-base complexes due to steric hindrance. They are capable of metal-free H2... -
Solution structures of aqua complexes of uranium in different oxidation states
The safe storage of spent nuclear fuels in an underground repository requires the fundamental chemistry to be well understood so predictions of solubility behaviour over 100,000... -
Why is Choline Arginate the Best Performing Bio-IL for Biomass Pretreatment?
The ionic liquid choline arginate [Ch][Arg] is more effective for coal pretreatment than other choline based amino acid ILs, but the underlying mechanism is unclear.... -
Structure of protic ionic liquids mixed with formamide derivatives.
Mixtures of protic ionic liquids (PIL) and polar, protic molecular liquids (MLs) are attracting great attention. Due to the ionic nature of PILs and the role of hydrogen bonding... -
Hydration structure of 5-phenyl tetrazolate in LCST ionic liquids
The interaction of water molecules with a model ammonium phenyltetrazolate ionic liquid will be studied to determine the dominant structures present as a function of water... -
Study of Association of Novel Zwitterionic Materials in Aqeous Solution for E...
New polyionic zwiterionic salts have been developed that show extreme hydrophilicity, offering potential to form microsegregated structures in the presence of water. In these... -
The hydration structure in potassium borate solutions
Borate solution is a much peculiar substance, in which not only hydrated cation but also varied borate speciation such as [B3O3(OH)4], [B4O5(OH)42], [B(OH)4] and [B(OH)3] are...