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Misfit and Misfit Release in Co-Co3(Al,W) Superalloys
The effect of alloying additions (Ni, Fe, Cr, Ta, Mo, V, Ti, Si) on the misfit of developmental Co-Al-W alloys will be examined using Polaris. The Co3(Al,W) precipitate phase... -
A high-temperature neutron powder determination of the phase transition and c...
Cu2ZnSnS4 (CZTS) is a solar cell material of great interest. However the material when fabricated, although of high symmetry, contains substantial defect concentration and a... -
Phase behaviour and dielectric phenomena in bismuth niobate energy storage ma...
Bismuth niobate (BiNbO4) is widely used in multilayer RF and microwave components such as capacitors and chip layer capacitors. This compound exhibits two main structural forms... -
A variable temperature study of polymorphism in Li2MSiO4 electrode materials
There is great interest in scaling up Li-ion batteries for use in electric vehicles, requiring cheap and safe cathodes. Recently, silicate-based cathodes have been described,... -
Structural phase transitions in Li doped AgNbO3.
The aims of the present proposal are twofold. Firstly to use very high resolution neutron diffraction data to establish accurate and precise structures of the novel... -
Structral characterisation of a novel lead free perovskite layer structure an...
Lead free antiferroelectric materials are the focus of much attention for the replacement of lead based materials in electronic devices, such as high energy storage capacitors,... -
The crystal structure and thermal expansion of orthorhombic NiSi
NiSi is a technologically important material that is also of interest to Earth Scientists because of the possible role of Ni and Si in the Earth¿s core. It crystallises in the... -
Understanding the decomposition of ammonia by lithium-calcium imide
Among light metal amide-imide catalysts for ammonia decomposition, lithium-calcium imide is the most promising candidate for practical application. Ex situ diffraction data... -
Phase transitions in Sr-doped multiferroic bismuth ferrite
Bismuth ferrite, BiFeO3, is a much-studied ceramic showing both dielectric and magnetic ordering at relatively high temperatures. In order to improve its properties there has... -
Programme Access Rosseinsky
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Improper ferroelectricity in hexagonal tungsten bronzes
Ferroelectrics are an important class of materials in modern electronics. Their application range from simple capacitors to ultrasonics transducers and sensors to memory... -
Hydrogen production from ammonia using lithium imide: an isotope study
We have recently discovered that light metal amides and imides are excellent cattalysts for the decomposition of ammonia. We request 3 days on POLARIS to perform in situ neutron... -
Investigation into the Effect of Heating Rates on Recrystallisation Mechanism...
Electrical steels (ES) used in motors and transformers. The major challenge is to optimise themagnetic property of ES to reduce energy waste during service. The crystallographic... -
The possibility of strongly ferromagnetic austenite in a stainless steel
It is generally accepted that austenitic steels (fcc) show no ferromagnetic signature. However, thermomagnetic measurements suggest an unexpected ferromagnetic transition (Tc =... -
Cation site disorder in KTiOPO4 isostructures
KTiOPO4 (KTP) is a well known non-linear optical material. Its crystal structure has highly asymmetric Ti-O bonds, a rigid TiO6-PO4 lattice and K cations trapped in cages. The... -
Relaxor-like dielectric behaviour in stoichiometric Sillenite Bi12SiO20
We request 1 day of beam-time on POLARIS to collect Neutron Diffraction (ND) data on the Sillenite Bi12SiO20 (gamma-Bi2O3) that we have recently discovered to exhibit a... -
Probing the Local Structure-Property Relationship in the IMSSZ Oxide Ion Cond...
The current state-of-the-art solid oxide fuel cell (SOFC) electrolyte material, 8 mol% yttria stabilised zirconia (8YSZ), exhibits good performance at temperatures above 850 °C.... -
Pressure effect on high-temperature multiferroic CuO studied by a single crys...
We propose to perform neutron diffraction experiment under high pressure condition, using a single crystal of CuO on WISH beamline. This monoxide is known as a multiferroic... -
Investigation into the Effect of Heating Rates on Recrystallisation Mechanism...
Electrical steels (ES) used in motors and transformers. The major challenge is to optimise the magnetic property of ES to reduce energy waste during service. The... -
Ammonia synthesis using lithium hydride-metal nitride composites: an in situ ...
The development of more active catalysts for the production of ammonia will have a worldwide impact on the energy cost of producing fertiliser. Composites of lithium hydride and...